从结构到功能:利用共价有机框架的离子传导性

IF 1.7 4区 化学 Bulletin of the Korean Chemical Society Pub Date : 2024-02-08 DOI:10.1002/bkcs.12823
Cong-Xue Liu, Soomin Hwang, Hyerin Woo, Eunsung Lee, Sarah S. Park
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引用次数: 0

摘要

在储能设备需求不断增长的推动下,储能技术突飞猛进,这凸显了理解离子传导行为的迫切需要。因此,对高性能离子导体的深入研究势在必行。共价有机框架(COFs)利用其独特的性能,如显著的多孔性、可调性和强大的物理化学耐久性,已成为固态或准固态离子传导领域的宝贵材料。这些独特的属性使 COFs 成为开发电极、电解质和分离器材料的理想候选材料,这些材料具有高容量、快速离子传输和电化学稳定性等特点。本综述深入探讨了作为离子导体的 COFs,讨论了基于 COF 的储能设备的最新进展,并探讨了结构功能化、孔径工程和尺寸调节对离子传导的影响。此外,该综述还旨在加深对 COFs 的理解,并为未来在储能技术中利用 COFs 取得进展铺平道路。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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From structure to function: Harnessing the ionic conductivity of covalent organic frameworks

Rapid advancements in energy storage technology, driven by a growing demand for energy storage devices, underscore the crucial need to comprehend ionic conduction behavior. Consequently, intensive research on high-performance ionic conductors becomes imperative. Covalent organic frameworks (COFs) have emerged as invaluable materials in the realm of solid-state or quasi-solid-state ion-conduction, leveraging their unique properties such as significant porosity, tunability, and robust physicochemical durability. These distinctive attributes position COFs as promising candidates for the development of electrodes, electrolytes, and separator materials characterized by high capacities, rapid ion transport, and electrochemical stability. This review provides insights into COFs as ionic conductors, discusses recent advancements in COF-based energy storage devices, and explores the influence of structural functionalization, pore size engineering, and dimensional regulation on ionic conduction. Moreover, the review aims to deepen understanding and pave the way for future advancements in the utilization of COFs within energy storage technologies.

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来源期刊
Bulletin of the Korean Chemical Society
Bulletin of the Korean Chemical Society Chemistry-General Chemistry
自引率
23.50%
发文量
182
期刊介绍: The Bulletin of the Korean Chemical Society is an official research journal of the Korean Chemical Society. It was founded in 1980 and reaches out to the chemical community worldwide. It is strictly peer-reviewed and welcomes Accounts, Communications, Articles, and Notes written in English. The scope of the journal covers all major areas of chemistry: analytical chemistry, electrochemistry, industrial chemistry, inorganic chemistry, life-science chemistry, macromolecular chemistry, organic synthesis, non-synthetic organic chemistry, physical chemistry, and materials chemistry.
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