{"title":"一种用于清洁剂和洗涤剂的可持续糖脂水溶液增溶剂","authors":"Marie-Françoise Chirac, Sophie Cambos, Jérôme Guilbot, Corinne Nawrocki, Régis Marchand, Alicia Roso","doi":"10.1002/jsde.12752","DOIUrl":null,"url":null,"abstract":"<p>Alkyl polyglycosides (APGs), based on renewable glucose and fatty alcohols, are recognized for their performance and biodegradability. Hydrotropic/solubilizing effect properties have already been identified on short-chain variants such as hexyl and ethylhexyl, but these ingredients were not fully bio-based. This study investigated the hydrotropic/solubilizing properties of eco-designed 100% bio-based heptyl glucoside, under various conditions, compared to industrial and personal care benchmarks and other short chain APGs. Foaming power was firstly evaluated at different temperatures with two static methods. Hydrotropic performance was assessed with a commonly used surfactant in the presence of high electrolyte, acid and alkali concentrations. Further trials were done using ethoxylated rapeseed oil as an oil lubricant model in electrolyte-charged aqueous solution. The solubilizing effect of hydrophobic additives such as fragrances, essential oils and vitamin E was quantified. Finally, effects on formulation preservation were screened with two natural personal care preservatives. Heptyl glucoside was found to be an effective and versatile hydrotrope for industrial applications, with additional intrinsic lubrication properties. It was also revealed as an efficient solubilizer for personal care products with the additional benefit of reducing the preservative dosage required in natural formulations. Its unusual non-foaming nature, while not disrupting the foaming capacity of surfactants, makes it suitable for all types of cleansers. The calculated carbon footprint has a low value, making heptyl glucoside a valuable ingredient combining both performance and low environmental impact.</p>","PeriodicalId":17083,"journal":{"name":"Journal of Surfactants and Detergents","volume":null,"pages":null},"PeriodicalIF":1.6000,"publicationDate":"2024-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/jsde.12752","citationCount":"0","resultStr":"{\"title\":\"A sustainable glycolipid hydrotrope-solubilizer for cleansers and detergents\",\"authors\":\"Marie-Françoise Chirac, Sophie Cambos, Jérôme Guilbot, Corinne Nawrocki, Régis Marchand, Alicia Roso\",\"doi\":\"10.1002/jsde.12752\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Alkyl polyglycosides (APGs), based on renewable glucose and fatty alcohols, are recognized for their performance and biodegradability. 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Heptyl glucoside was found to be an effective and versatile hydrotrope for industrial applications, with additional intrinsic lubrication properties. It was also revealed as an efficient solubilizer for personal care products with the additional benefit of reducing the preservative dosage required in natural formulations. Its unusual non-foaming nature, while not disrupting the foaming capacity of surfactants, makes it suitable for all types of cleansers. 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引用次数: 0
摘要
以可再生葡萄糖和脂肪醇为基础的烷基多糖苷(APGs)因其性能和生物降解性而广受认可。短链变体(如己基和乙基己基)的亲水/增溶效果特性已经得到确认,但这些成分并非完全以生物为基础。本研究调查了生态设计的 100% 生物基庚基葡糖苷在各种条件下的亲水/增溶特性,并与工业和个人护理基准以及其他短链 APG 进行了比较。首先用两种静态方法评估了在不同温度下的发泡力。在电解质、酸和碱浓度较高的情况下,使用一种常用的表面活性剂对其亲水性能进行了评估。此外,还使用乙氧基化菜籽油作为电解质水溶液中的油润滑剂模型进行了进一步试验。对香料、精油和维生素 E 等疏水添加剂的增溶效果进行了量化。最后,筛选了两种天然个人护理防腐剂对配方防腐的影响。研究发现,庚基葡萄糖苷是一种可用于工业用途的有效、多用途的亲水物质,具有额外的内在润滑特性。此外,它还是个人护理产品的高效增溶剂,还能减少天然配方中所需的防腐剂用量。它非同寻常的不起泡特性不会破坏表面活性剂的起泡能力,因此适用于所有类型的清洁剂。计算得出的碳足迹值较低,因此庚基葡萄糖苷是一种兼具高性能和低环境影响的珍贵成分。
A sustainable glycolipid hydrotrope-solubilizer for cleansers and detergents
Alkyl polyglycosides (APGs), based on renewable glucose and fatty alcohols, are recognized for their performance and biodegradability. Hydrotropic/solubilizing effect properties have already been identified on short-chain variants such as hexyl and ethylhexyl, but these ingredients were not fully bio-based. This study investigated the hydrotropic/solubilizing properties of eco-designed 100% bio-based heptyl glucoside, under various conditions, compared to industrial and personal care benchmarks and other short chain APGs. Foaming power was firstly evaluated at different temperatures with two static methods. Hydrotropic performance was assessed with a commonly used surfactant in the presence of high electrolyte, acid and alkali concentrations. Further trials were done using ethoxylated rapeseed oil as an oil lubricant model in electrolyte-charged aqueous solution. The solubilizing effect of hydrophobic additives such as fragrances, essential oils and vitamin E was quantified. Finally, effects on formulation preservation were screened with two natural personal care preservatives. Heptyl glucoside was found to be an effective and versatile hydrotrope for industrial applications, with additional intrinsic lubrication properties. It was also revealed as an efficient solubilizer for personal care products with the additional benefit of reducing the preservative dosage required in natural formulations. Its unusual non-foaming nature, while not disrupting the foaming capacity of surfactants, makes it suitable for all types of cleansers. The calculated carbon footprint has a low value, making heptyl glucoside a valuable ingredient combining both performance and low environmental impact.
期刊介绍:
Journal of Surfactants and Detergents, a journal of the American Oil Chemists’ Society (AOCS) publishes scientific contributions in the surfactants and detergents area. This includes the basic and applied science of petrochemical and oleochemical surfactants, the development and performance of surfactants in all applications, as well as the development and manufacture of detergent ingredients and their formulation into finished products.