具有用 Fe2O3 纳米粒子修饰的短尺寸通道的 SBA-15。一种用于去除污染水中砷的新型近似高效吸附剂

IF 2.5 4区 材料科学 Q2 CHEMISTRY, APPLIED Journal of Porous Materials Pub Date : 2024-04-13 DOI:10.1007/s10934-024-01589-6
Viviana Palos-Barba, Rufino Nava Mendoza, Beatriz M. Millán-Malo, Manuel Aguilar-Franco, Carmen Peza-Ledesma, Eric M. Rivera-Muñoz
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引用次数: 0

摘要

根据联合国制定的可持续发展目标,迫切需要确保健康标准的技术,这促使人们研究如何解决与空气、水和土壤中的化学污染物相关的人类健康问题。重金属,尤其是砷,对健康构成了极大的威胁,全世界有数百万人暴露在浓度超过建议限值的环境中。纳米结构材料,包括有序介孔基质(如 SBA-15),因其高比表面和孔隙特征,在砷去除方面前景看好。本研究旨在合成一种孔道长度减少的二氧化硅介孔材料,以增加表面积和活性位点,从而提高砷去除效率。通过探索各种表面活性剂与二氧化硅前驱体的比例,确定了一个合适的值,以促进缩短 SBA-15 颗粒的生产。这些缩短的孔道有利于氧化铁纳米颗粒(Fe2O3)在 SBA-15 表面的分散,从而产生了一种有效的吸附剂,砷去除率超过 95%。改性 SBA-15 基质与 Fe2O3 纳米粒子的结合显示了从水体污水中去除砷的高效率,为解决水污染和相关健康风险问题提供了一种前景广阔的解决方案。
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SBA-15 with short-sized channels modified with Fe2O3 nanoparticles. A novel approximation of an efficient adsorbent for As removal in contaminated water

The urgent need for technologies to ensure health standards, as per the Sustainable Development Goals established by the United Nations, has prompted research into addressing human health problems associated with chemical contaminants in air, water, and soil. Heavy metals, particularly arsenic, pose significant health risks, with millions of people worldwide exposed to concentrations exceeding recommended limits. Nanostructured materials, including ordered mesoporous substrates such as SBA-15, have shown promise for arsenic removal due to their high surface area and pore characteristics. This study aimed to synthesize a silica mesoporous material with reduced pore channel length to enhance surface area and active sites, thereby improving arsenic removal efficiency. By exploring various surfactant-to-silica precursor ratios, a suitable value was identified to promote the production of shortened SBA-15 particles. These shortened pore channels facilitated the dispersion of iron oxide nanoparticles (Fe2O3) on the SBA-15 surface, resulting in an effective adsorbent that achieved over 95% arsenic removal. The combination of the modified SBA-15 substrate and Fe2O3 nanoparticles demonstrated high efficiency in arsenic removal from aqueous effluents, offering a promising solution to address water pollution and associated health risks.

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来源期刊
Journal of Porous Materials
Journal of Porous Materials 工程技术-材料科学:综合
CiteScore
4.80
自引率
7.70%
发文量
203
审稿时长
2.6 months
期刊介绍: The Journal of Porous Materials is an interdisciplinary and international periodical devoted to all types of porous materials. Its aim is the rapid publication of high quality, peer-reviewed papers focused on the synthesis, processing, characterization and property evaluation of all porous materials. The objective is to establish a unique journal that will serve as a principal means of communication for the growing interdisciplinary field of porous materials. Porous materials include microporous materials with 50 nm pores. Examples of microporous materials are natural and synthetic molecular sieves, cationic and anionic clays, pillared clays, tobermorites, pillared Zr and Ti phosphates, spherosilicates, carbons, porous polymers, xerogels, etc. Mesoporous materials include synthetic molecular sieves, xerogels, aerogels, glasses, glass ceramics, porous polymers, etc.; while macroporous materials include ceramics, glass ceramics, porous polymers, aerogels, cement, etc. The porous materials can be crystalline, semicrystalline or noncrystalline, or combinations thereof. They can also be either organic, inorganic, or their composites. The overall objective of the journal is the establishment of one main forum covering the basic and applied aspects of all porous materials.
期刊最新文献
Correction: One-step synthesis of CuO/MCM-41 nanocomposites and their application in photocatalytic degradation of dyes Modification of SBA-15 for stabilizing supported oxides Lotus leaf-derived capacitive carbon for zinc-ion hybrid supercapacitors prepared by one-step molten salt carbonization Influence of various templates on the performance of MFI zeolite in catalytic synthesis of trioxane Facile synthesis of copper sulfide loaded mesoporous organosilica nanospheres with a triple-shelled hollow structure
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