以化学计量学为工具,监测所选合金在实际条件下的腐蚀降解情况

IF 2.3 4区 化学 Q1 SOCIAL WORK Journal of Chemometrics Pub Date : 2024-04-16 DOI:10.1002/cem.3551
Gyöngyi Vastag, Suzana Apostolov, Špiro Ivošević, Rebeka Rudolf
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引用次数: 0

摘要

在实际条件下监测合金的腐蚀过程往往会获得大量数据,这些数据的特点是相互依存关系复杂,但相互偏差较大。首先,由于获得的结果非常分散,因此很难就测试参数对合金腐蚀行为的实际影响得出准确的结论。另一方面,在许多情况下,腐蚀因素之间的高度相互依赖性也会给分析系统带来很大负担,从而使识别主要影响因素变得十分困难。多元分析,尤其是主成分分析,由于其识别和消除冗余数据的能力,在处理这类数据时越来越受欢迎。本研究的目的是探讨在处理实际条件下获得的腐蚀测试结果时使用多元分析方法的可能性。根据所获得的结果,可以得出结论:结合能量色散光谱仪分析使用的多元方法可以成功用于识别最重要的腐蚀因素(腐蚀环境类型、暴露时间和技术生产流程),以及它们在给定条件下对测试钛镍合金降解的影响。
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Chemometrics as a tool for monitoring corrosion degradation of the selected alloys in real conditions

Monitoring of the corrosion process of alloys in real conditions often results in extensive data, which is characterized by complex interdependence, but by a large degree of mutual deviation. First of all, the large dispersion of the obtained results makes it very difficult to draw accurate conclusions about the real influence of the tested parameters on the corrosion behavior of alloys. On the other hand, in many cases, the high interdependence between the corrosion factors can also greatly burden the analyzed system and thus make it significantly difficult to recognize the main influence. Multivariate analysis, especially the principal component analysis, is becoming increasingly popular in processing of this type of data, due to its ability to recognize and eliminate redundant data. The aim of this study was to examine the possibility of using multivariate analysis methods in the processing of the corrosion test results obtained under real conditions. Based on the obtained results, it can be concluded that used multivariate method in combination with energy dispersive spectrometer analysis can be successfully used to identify the most important corrosion factors (type of corrosion environment, exposure time and technological production processes), as well as their influence on the degradation of the tested TiNi alloys under the given conditions.

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来源期刊
Journal of Chemometrics
Journal of Chemometrics 化学-分析化学
CiteScore
5.20
自引率
8.30%
发文量
78
审稿时长
2 months
期刊介绍: The Journal of Chemometrics is devoted to the rapid publication of original scientific papers, reviews and short communications on fundamental and applied aspects of chemometrics. It also provides a forum for the exchange of information on meetings and other news relevant to the growing community of scientists who are interested in chemometrics and its applications. Short, critical review papers are a particularly important feature of the journal, in view of the multidisciplinary readership at which it is aimed.
期刊最新文献
Issue Information Cover Image Past, Present and Future of Research in Analytical Figures of Merit Analytical Figures of Merit in Univariate, Multivariate, and Multiway Calibration: What Have We Learned? What Do We Still Need to Learn? Paul Geladi (1951–2024) Chemometrician, spectroscopist and pioneer
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