E. R. Belyaeva, Yu. G. Borisova, G. Z. Raskildina, R. M. Sultanova, S. S. Zlotsky
{"title":"通过低温臭氧分解 1,3-二氧杂环庚烷合成含乙缩醛片段的多官能团 O 型化合物","authors":"E. R. Belyaeva, Yu. G. Borisova, G. Z. Raskildina, R. M. Sultanova, S. S. Zlotsky","doi":"10.1134/S0012500824600081","DOIUrl":null,"url":null,"abstract":"<p>3,5-Dioxo-1,7-heptanedials, 3,5-dioxo-1,7-heptanediols, and derivatives of 1,3-dioxo-1,7-heptanediboxylic acid have been synthesized for the first time by the low-temperature ozonolysis of 1,3-dioxepins. It has been shown that intermediate ozonolysis products, peroxy compounds, depending on decomposition conditions can produce corresponding individual dialdehydes, diols, and diesters with high selectivity.</p>","PeriodicalId":530,"journal":{"name":"Doklady Chemistry","volume":"514 2","pages":"58 - 61"},"PeriodicalIF":0.8000,"publicationDate":"2024-04-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis of Polyfunctional O-Containing Compounds with Acetal Fragment by Low-Temperature Ozonolysis of 1,3-Dioxepins\",\"authors\":\"E. R. Belyaeva, Yu. G. Borisova, G. Z. Raskildina, R. M. Sultanova, S. S. Zlotsky\",\"doi\":\"10.1134/S0012500824600081\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>3,5-Dioxo-1,7-heptanedials, 3,5-dioxo-1,7-heptanediols, and derivatives of 1,3-dioxo-1,7-heptanediboxylic acid have been synthesized for the first time by the low-temperature ozonolysis of 1,3-dioxepins. It has been shown that intermediate ozonolysis products, peroxy compounds, depending on decomposition conditions can produce corresponding individual dialdehydes, diols, and diesters with high selectivity.</p>\",\"PeriodicalId\":530,\"journal\":{\"name\":\"Doklady Chemistry\",\"volume\":\"514 2\",\"pages\":\"58 - 61\"},\"PeriodicalIF\":0.8000,\"publicationDate\":\"2024-04-13\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Doklady Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S0012500824600081\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Doklady Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S0012500824600081","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Synthesis of Polyfunctional O-Containing Compounds with Acetal Fragment by Low-Temperature Ozonolysis of 1,3-Dioxepins
3,5-Dioxo-1,7-heptanedials, 3,5-dioxo-1,7-heptanediols, and derivatives of 1,3-dioxo-1,7-heptanediboxylic acid have been synthesized for the first time by the low-temperature ozonolysis of 1,3-dioxepins. It has been shown that intermediate ozonolysis products, peroxy compounds, depending on decomposition conditions can produce corresponding individual dialdehydes, diols, and diesters with high selectivity.
期刊介绍：
Doklady Chemistry is a journal that publishes new research in chemistry and chemical engineering of great significance. Initially the journal was a forum of the Russian Academy of Science and published only best contributions from Russia in the form of short articles. Now the journal welcomes submissions from any country in the English or Russian language. Every manuscript must be recommended by Russian or foreign members of the Russian Academy of Sciences.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
