液体中氮氧化物功率饱和自旋模式的实验研究 1

IF 1.1 4区 物理与天体物理 Q4 PHYSICS, ATOMIC, MOLECULAR & CHEMICAL Applied Magnetic Resonance Pub Date : 2024-04-19 DOI:10.1007/s00723-024-01651-1
Barney L. Bales, Miroslav Peric, Robert N. Schwartz
{"title":"液体中氮氧化物功率饱和自旋模式的实验研究 1","authors":"Barney L. Bales,&nbsp;Miroslav Peric,&nbsp;Robert N. Schwartz","doi":"10.1007/s00723-024-01651-1","DOIUrl":null,"url":null,"abstract":"<div><p>In recent years, the theory of the effect of saturation of EPR spectra of free radicals undergoing spin exchange has been extended to spin exchange frequencies where “peculiar” behavior occurs. In a paper by Salikhov (Appl. Magn. Reson. (2021) <b>52</b>:1063–1091), analytic expressions were developed that predict the dependence of measurable EPR parameters on the exchange frequencies and the microwave field strength. This work is an experimental test of that theory where, in principle, there are no adjustable parameters.</p></div>","PeriodicalId":469,"journal":{"name":"Applied Magnetic Resonance","volume":"55 9","pages":"1115 - 1127"},"PeriodicalIF":1.1000,"publicationDate":"2024-04-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Experimental Studies of Power-Saturated Spin Modes of Nitroxides in Liquids 1\",\"authors\":\"Barney L. Bales,&nbsp;Miroslav Peric,&nbsp;Robert N. Schwartz\",\"doi\":\"10.1007/s00723-024-01651-1\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>In recent years, the theory of the effect of saturation of EPR spectra of free radicals undergoing spin exchange has been extended to spin exchange frequencies where “peculiar” behavior occurs. In a paper by Salikhov (Appl. Magn. Reson. (2021) <b>52</b>:1063–1091), analytic expressions were developed that predict the dependence of measurable EPR parameters on the exchange frequencies and the microwave field strength. This work is an experimental test of that theory where, in principle, there are no adjustable parameters.</p></div>\",\"PeriodicalId\":469,\"journal\":{\"name\":\"Applied Magnetic Resonance\",\"volume\":\"55 9\",\"pages\":\"1115 - 1127\"},\"PeriodicalIF\":1.1000,\"publicationDate\":\"2024-04-19\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Applied Magnetic Resonance\",\"FirstCategoryId\":\"101\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s00723-024-01651-1\",\"RegionNum\":4,\"RegionCategory\":\"物理与天体物理\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"PHYSICS, ATOMIC, MOLECULAR & CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Applied Magnetic Resonance","FirstCategoryId":"101","ListUrlMain":"https://link.springer.com/article/10.1007/s00723-024-01651-1","RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"PHYSICS, ATOMIC, MOLECULAR & CHEMICAL","Score":null,"Total":0}
引用次数: 0

摘要

近年来,关于发生自旋交换的自由基的 EPR 光谱饱和效应的理论已扩展到发生 "奇特 "行为的自旋交换频率。在萨利霍夫(Salikhov)的一篇论文(Appl.Reson.(2021) 52:1063-1091)中,建立了分析表达式,预测了可测量的 EPR 参数对交换频率和微波场强的依赖性。这项工作是对该理论的实验测试,原则上不存在可调整的参数。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

摘要图片

摘要图片

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
Experimental Studies of Power-Saturated Spin Modes of Nitroxides in Liquids 1

In recent years, the theory of the effect of saturation of EPR spectra of free radicals undergoing spin exchange has been extended to spin exchange frequencies where “peculiar” behavior occurs. In a paper by Salikhov (Appl. Magn. Reson. (2021) 52:1063–1091), analytic expressions were developed that predict the dependence of measurable EPR parameters on the exchange frequencies and the microwave field strength. This work is an experimental test of that theory where, in principle, there are no adjustable parameters.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Applied Magnetic Resonance
Applied Magnetic Resonance 物理-光谱学
CiteScore
1.90
自引率
10.00%
发文量
59
审稿时长
2.3 months
期刊介绍: Applied Magnetic Resonance provides an international forum for the application of magnetic resonance in physics, chemistry, biology, medicine, geochemistry, ecology, engineering, and related fields. The contents include articles with a strong emphasis on new applications, and on new experimental methods. Additional features include book reviews and Letters to the Editor.
期刊最新文献
Deep-Learning Segmentation of Bleomycin-Induced Pulmonary Fibrosis in Rats Using U-Net 3 + by 3D UTE-MRI Influence of Ge concentration on magnetic properties of \(\hbox {Co}_{(1-x)} \hbox {Ge}_{x}\) thin films A Method for Analyzing Data from 1- and 2-Dimensional Relaxation and Diffusion NMR Experiments by Determination of their Expectation Values and Standard Deviations Photocurrent EDMR Measurement and Carrier Behavior of TIPS-Pentacene Under FET Device Operation Nitroxide Spin Labels for Exploring Relationships Between Molecular Structure, Microenvironment and EPR Parameters: A Mini-review Dedicated to Carlo Corvaja
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1