A. Athique Ahmed, Ancy Kurian, S. Abima, S. Sumathi
{"title":"CeO2 耦合对 CePO4 纳米粒子的结构、光学和光催化性能的影响","authors":"A. Athique Ahmed, Ancy Kurian, S. Abima, S. Sumathi","doi":"10.1134/s0018143924020024","DOIUrl":null,"url":null,"abstract":"<h3 data-test=\"abstract-sub-heading\">Abstract</h3><p>This research work presents the synthesis and characterization of CeO<sub>2</sub> coupled CePO<sub>4</sub> nanocomposites using a hydrothermal technique to examine the coupled composites photocatalytic activity. Stru-ctural, optical and morphological characteristics of the compounds were analysed using XRD, FTIR, UV-DRS, PL, SEM, and EDS techniques. Rietveld refinement provided valuable insights into their structural properties. A 3D model was constructed to illustrate the successful coupling of CeO<sub>2</sub> and CePO<sub>4</sub>. The photocatalytic performance of CePO<sub>4</sub> was significantly increased by coupling with CeO<sub>2</sub>, and the C70 (70 : 30 weight ratio of CeO<sub>2</sub> and CePO<sub>4</sub>) composite exhibited the highest degradation efficiency for RhB and MO dyes. Reactive oxygen species analysis was conducted to attribute the mechanism of the coupled composite. Furthermore, the synthesized composites demonstrated excellent specificity, stability, and reusability.</p>","PeriodicalId":12893,"journal":{"name":"High Energy Chemistry","volume":"38 1","pages":""},"PeriodicalIF":0.9000,"publicationDate":"2024-04-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Effect of CeO2 Coupling on the Structural, Optical and Photocatalytic Performance of CePO4 Nanoparticles\",\"authors\":\"A. Athique Ahmed, Ancy Kurian, S. Abima, S. Sumathi\",\"doi\":\"10.1134/s0018143924020024\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<h3 data-test=\\\"abstract-sub-heading\\\">Abstract</h3><p>This research work presents the synthesis and characterization of CeO<sub>2</sub> coupled CePO<sub>4</sub> nanocomposites using a hydrothermal technique to examine the coupled composites photocatalytic activity. Stru-ctural, optical and morphological characteristics of the compounds were analysed using XRD, FTIR, UV-DRS, PL, SEM, and EDS techniques. Rietveld refinement provided valuable insights into their structural properties. A 3D model was constructed to illustrate the successful coupling of CeO<sub>2</sub> and CePO<sub>4</sub>. The photocatalytic performance of CePO<sub>4</sub> was significantly increased by coupling with CeO<sub>2</sub>, and the C70 (70 : 30 weight ratio of CeO<sub>2</sub> and CePO<sub>4</sub>) composite exhibited the highest degradation efficiency for RhB and MO dyes. Reactive oxygen species analysis was conducted to attribute the mechanism of the coupled composite. Furthermore, the synthesized composites demonstrated excellent specificity, stability, and reusability.</p>\",\"PeriodicalId\":12893,\"journal\":{\"name\":\"High Energy Chemistry\",\"volume\":\"38 1\",\"pages\":\"\"},\"PeriodicalIF\":0.9000,\"publicationDate\":\"2024-04-21\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"High Energy Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1134/s0018143924020024\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"High Energy Chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1134/s0018143924020024","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Effect of CeO2 Coupling on the Structural, Optical and Photocatalytic Performance of CePO4 Nanoparticles
Abstract
This research work presents the synthesis and characterization of CeO2 coupled CePO4 nanocomposites using a hydrothermal technique to examine the coupled composites photocatalytic activity. Stru-ctural, optical and morphological characteristics of the compounds were analysed using XRD, FTIR, UV-DRS, PL, SEM, and EDS techniques. Rietveld refinement provided valuable insights into their structural properties. A 3D model was constructed to illustrate the successful coupling of CeO2 and CePO4. The photocatalytic performance of CePO4 was significantly increased by coupling with CeO2, and the C70 (70 : 30 weight ratio of CeO2 and CePO4) composite exhibited the highest degradation efficiency for RhB and MO dyes. Reactive oxygen species analysis was conducted to attribute the mechanism of the coupled composite. Furthermore, the synthesized composites demonstrated excellent specificity, stability, and reusability.
期刊介绍：
High Energy Chemistry publishes original articles, reviews, and short communications on molecular and supramolecular photochemistry, photobiology, radiation chemistry, plasma chemistry, chemistry of nanosized systems, chemistry of new atoms, processes and materials for optical information systems and other areas of high energy chemistry. It publishes theoretical and experimental studies in all areas of high energy chemistry, such as the interaction of high-energy particles with matter, the nature and reactivity of short-lived species induced by the action of particle and electromagnetic radiation or hot atoms on substances in their gaseous and condensed states, and chemical processes initiated in organic and inorganic systems by high-energy radiation.
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