Experimental Investigation of Phase Equilibria in the Ti-Cr-V System at 1000–1200 °C

Ti-Cr-V-based alloys have been utilized across various domains, including aerospace structural and functional materials and hydrogen storage materials. Investigating the phase relations in the Ti-Cr-V system is significant in supporting the material design for these applications. In the present work, the isothermal sections at 1000, 1100, and 1200 °C for the Ti-Cr-V system were precisely determined through a systematic investigation using scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), and X-ray diffraction (XRD). The phase region of Cr2Ti was entirely elucidated for the first time. As the temperature decreased from 1200 to 1000 °C, the V solubility range of Cr2Ti increased from 5.3 wt.% to 10.0 wt.%, while the Ti solubility range essentially remained constant at approximately 31.0–33.9 wt.%. In addition, it was suggested that the stable structure of Cr2Ti was C36 at 1200 °C and C15 at 1000 and 1100 °C. The present work will support thermodynamic re-assessment research.