{"title":"AP 分布对 HMX/AP/Al 炸药能量释放特性和作用力的影响","authors":"Han Gao, Wen Pan, Xiao-Jun Feng","doi":"10.1002/prep.202300263","DOIUrl":null,"url":null,"abstract":"In order to understand the reaction kinetics of HMX/AP/Al ternary system, the different distribution of AP in HMX/AP/Al explosives was realized by two different preparation techniques. Detonation test results show that the detonation velocity, explosion heat and detonation pressure of HAP samples are higher than those of HAl samples, but the extent of improvement is not high, not more than 5 %. The results of scanning electron microscopy showed that AP in HAP samples was distributed on the surface of HMX crystal. AP were dispersed around HMX crystals in HAl samples. The experimental results of explosive fireball performance show that the fireball expansion speed of HAP samples is better than that of HAl samples, demonstrating a good fireball effect. Underwater test results show that the shock wave peak pressure and bubble pulsation period of HAP samples increase by 3.06 % and 7.95 % respectively, and shock wave energy and bubble energy increase by 9.8 % and 25.42 % compared with bubble energy. The experimental results show that HAP samples are superior to HAl samples in accelerating ability of Al flies. The dispersion of AP on the HMX crystal surface promotes the energy release of HMX/AP/Al explosives more.","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":"32 12","pages":""},"PeriodicalIF":17.7000,"publicationDate":"2024-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Effect of AP distribution on energy release characteristics and functional force of HMX/AP/Al explosives\",\"authors\":\"Han Gao, Wen Pan, Xiao-Jun Feng\",\"doi\":\"10.1002/prep.202300263\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"In order to understand the reaction kinetics of HMX/AP/Al ternary system, the different distribution of AP in HMX/AP/Al explosives was realized by two different preparation techniques. Detonation test results show that the detonation velocity, explosion heat and detonation pressure of HAP samples are higher than those of HAl samples, but the extent of improvement is not high, not more than 5 %. The results of scanning electron microscopy showed that AP in HAP samples was distributed on the surface of HMX crystal. AP were dispersed around HMX crystals in HAl samples. The experimental results of explosive fireball performance show that the fireball expansion speed of HAP samples is better than that of HAl samples, demonstrating a good fireball effect. Underwater test results show that the shock wave peak pressure and bubble pulsation period of HAP samples increase by 3.06 % and 7.95 % respectively, and shock wave energy and bubble energy increase by 9.8 % and 25.42 % compared with bubble energy. The experimental results show that HAP samples are superior to HAl samples in accelerating ability of Al flies. The dispersion of AP on the HMX crystal surface promotes the energy release of HMX/AP/Al explosives more.\",\"PeriodicalId\":1,\"journal\":{\"name\":\"Accounts of Chemical Research\",\"volume\":\"32 12\",\"pages\":\"\"},\"PeriodicalIF\":17.7000,\"publicationDate\":\"2024-04-22\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Accounts of Chemical Research\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://doi.org/10.1002/prep.202300263\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1002/prep.202300263","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
摘要
为了了解HMX/AP/Al三元体系的反应动力学,通过两种不同的制备技术实现了AP在HMX/AP/Al炸药中的不同分布。爆轰试验结果表明,HAP 样品的爆速、爆轰热和爆轰压力均高于 HAl 样品,但提高幅度不大,不超过 5%。扫描电子显微镜结果表明,HAP 样品中的 AP 分布在 HMX 晶体表面。在 HAl 样品中,AP 分散在 HMX 晶体周围。爆炸火球性能实验结果表明,HAP 样品的火球膨胀速度优于 HAl 样品,显示出良好的火球效果。水下测试结果表明,HAP 样品的冲击波峰值压力和气泡脉动周期分别增加了 3.06 % 和 7.95 %,冲击波能量和气泡能量与气泡能量相比分别增加了 9.8 % 和 25.42 %。实验结果表明,HAP 样品对铝蝇的加速能力优于 HAl 样品。AP 在 HMX 晶体表面的分散更能促进 HMX/AP/Al 炸药的能量释放。
Effect of AP distribution on energy release characteristics and functional force of HMX/AP/Al explosives
In order to understand the reaction kinetics of HMX/AP/Al ternary system, the different distribution of AP in HMX/AP/Al explosives was realized by two different preparation techniques. Detonation test results show that the detonation velocity, explosion heat and detonation pressure of HAP samples are higher than those of HAl samples, but the extent of improvement is not high, not more than 5 %. The results of scanning electron microscopy showed that AP in HAP samples was distributed on the surface of HMX crystal. AP were dispersed around HMX crystals in HAl samples. The experimental results of explosive fireball performance show that the fireball expansion speed of HAP samples is better than that of HAl samples, demonstrating a good fireball effect. Underwater test results show that the shock wave peak pressure and bubble pulsation period of HAP samples increase by 3.06 % and 7.95 % respectively, and shock wave energy and bubble energy increase by 9.8 % and 25.42 % compared with bubble energy. The experimental results show that HAP samples are superior to HAl samples in accelerating ability of Al flies. The dispersion of AP on the HMX crystal surface promotes the energy release of HMX/AP/Al explosives more.
期刊介绍:
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.