开发用于西米淀粉水解的地热污泥衍生二氧化硅催化剂

O.K. Ahmad Ariq, Widiana Nurrahmadhanti Bunga, E. M. Idzati, Firman Kurniawansyah, H. Ni’mah, H. B. T. M. Petrus, M. Mahfud
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摘要

硅基催化剂是利用印度尼西亚中爪哇省 Dieng 发电站的地热污泥(地热勘探产生的固体废物)制备的。催化剂的制备方法是从污泥基质中提取二氧化硅化合物,然后进行磺化处理,得到磺化固体催化剂。催化剂样品分析表明,催化剂一般呈无定形结构,表面积在 76 - 81 m2/g 之间,酸度约为 5-6 mmol/g。在常压和 100 - 150°C (373 - 423 K) 条件下,将催化剂用于西米淀粉水解,对催化剂活性进行了评估,结果显示转化率超过 90%。
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Development of Geothermal Sludge Derived - Silica Catalyst for Sago Starch Hydrolysis
Silica based catalyst was prepared from geothermal sludge – solid waste from geothermal exploration - of Dieng Power Station, Central Java, Indonesia. The catalyst was prepared by extracting silica compound from the sludge matrix, followed by sulfonation to obtain sulfonated – solid catalyst. Catalyst sample analysis informed the catalyst was generally amorphous in structures, possessed surface area between 76 – 81 m2/g, with acidity approximately 5-6 mmol/g. Evaluation on catalyst activity was performed by applying it on sago starch hydrolysis - atmospheric pressure and 100 – 150°C (373 – 423 K) - in which more than 90 % conversion could be achieved.
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