内电极形状对氧化去除 NO 和 SO2 的介质阻挡放电反应器性能的影响

Yunkai Cai, Bingfeng Huang, Fei Dong, Neng Zhu
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摘要

海轮承担着全球 90% 以上的货运量,但与此同时,海轮排放的污染物(氮氧化物和硫氧化物)也造成了严重的空气污染。非热等离子体(NTP)与湿式洗涤技术相结合被认为是一种前景广阔的技术。为了提高 NTP 反应器的氧化效率和能效,研究人员对介质阻挡放电(DBD)反应器的螺杆和杆内电极进行了研究。为分析其机理,测量了 NTP 的光发射光谱(OES)并进行了数值计算。实验结果表明,螺旋电极的 NO 氧化去除效率低于棒状电极。然而,螺旋电极对二氧化硫的去除效率较高。根据 OES 实验和数值计算,螺旋电极表面的电场强度远高于棒状电极表面,更容易产生 N 自由基生成 NO。在相同能量密度条件下,螺旋电极反应器的 OH 自由基生成效率与棒状电极相似,但放电间隙中的气体温度更高。因此,螺纹电极的 SO2 氧化效率更高。这项研究为优化 DBD 反应器的氧化效率和能耗提供了指导。
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The effects of inner electrode shape on the performance of dielectric barrier discharge reactor for oxidative removal of NO and SO2
Seagoing vessels are responsible for more than 90% of global freight traffic, but meanwhile, emission pollutants (NOx and SOx) of seagoing vessels also cause serious air pollution. Nonthermal plasma (NTP) combined with wet scrubbing technology is considered to be a promising technology. In order to improve the oxidation efficiency and energy efficiency of the NTP reactor, the screw and rod inner electrodes of dielectric barrier discharge (DBD) reactor were investigated. To analyze the mechanism, the optical emission spectra (OES) of NTP was measured and numerical calculation was applied. The experiment results show that the NO oxidation removal efficiency of screw electrode is lower than that of rod electrode. However, the SO2 removal efficiency of screw electrode is higher. According to the OES experiment and numerical calculation, the electric field intensity of the screw electrode surface is much higher than that of the rod electrode surface, and it is easier to generate N radicals to form NO. For the same energy density condition, the OH radical generation efficiency of the screw electrode reactor is similar to that of the rod electrode, but the gas temperature in the discharge gap is higher. Therefore, the SO2 oxidation efficiency of the thread electrode is higher. This study provides guidance for the optimization of oxidation efficiency and energy consumption of DBD reactor.
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