{"title":"吸附处理硝酸溶液以去除磷酸三丁酯和六氯丁二烯","authors":"V. V. Kulemin, S. A. Kulyukhin","doi":"10.1134/s1066362224010089","DOIUrl":null,"url":null,"abstract":"<h3 data-test=\"abstract-sub-heading\">Abstract</h3><p>The possibility of using the polymer sorbent Polysorb-1 for the treatment of nitric acid solutions to remove organophosphorus compounds, including tributyl phosphate (TBP) and hexachlorobutadiene (HCBD), is studied. It is shown that decontamination of nitric acid solutions containing organophosphorus compounds, HCBD, U(VI), and Pu(IV) with Polysorb-1 sorbent under dynamic conditions allows reducing the phosphorus and HCBD content to ~2 mg/dm<sup>3</sup> or less and to 0.05 mg/dm<sup>3</sup> or less, respectively. In this case, sorption of U(VI) and Pu(IV) does not occur. The procedures of vacuum distillation and overheated steam stripping are described for regeneration of Polysorb-1 sorbent containing TBP and HCBD. The optimal process temperature was chosen to be 170°C.</p>","PeriodicalId":747,"journal":{"name":"Radiochemistry","volume":null,"pages":null},"PeriodicalIF":0.9000,"publicationDate":"2024-04-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Sorption Treatment of Nitric Acid Solutions to Remove Tributyl Phosphate and Hexachlorobutadiene\",\"authors\":\"V. V. Kulemin, S. A. Kulyukhin\",\"doi\":\"10.1134/s1066362224010089\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<h3 data-test=\\\"abstract-sub-heading\\\">Abstract</h3><p>The possibility of using the polymer sorbent Polysorb-1 for the treatment of nitric acid solutions to remove organophosphorus compounds, including tributyl phosphate (TBP) and hexachlorobutadiene (HCBD), is studied. It is shown that decontamination of nitric acid solutions containing organophosphorus compounds, HCBD, U(VI), and Pu(IV) with Polysorb-1 sorbent under dynamic conditions allows reducing the phosphorus and HCBD content to ~2 mg/dm<sup>3</sup> or less and to 0.05 mg/dm<sup>3</sup> or less, respectively. In this case, sorption of U(VI) and Pu(IV) does not occur. The procedures of vacuum distillation and overheated steam stripping are described for regeneration of Polysorb-1 sorbent containing TBP and HCBD. The optimal process temperature was chosen to be 170°C.</p>\",\"PeriodicalId\":747,\"journal\":{\"name\":\"Radiochemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.9000,\"publicationDate\":\"2024-04-23\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Radiochemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1134/s1066362224010089\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Radiochemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1134/s1066362224010089","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Sorption Treatment of Nitric Acid Solutions to Remove Tributyl Phosphate and Hexachlorobutadiene
Abstract
The possibility of using the polymer sorbent Polysorb-1 for the treatment of nitric acid solutions to remove organophosphorus compounds, including tributyl phosphate (TBP) and hexachlorobutadiene (HCBD), is studied. It is shown that decontamination of nitric acid solutions containing organophosphorus compounds, HCBD, U(VI), and Pu(IV) with Polysorb-1 sorbent under dynamic conditions allows reducing the phosphorus and HCBD content to ~2 mg/dm3 or less and to 0.05 mg/dm3 or less, respectively. In this case, sorption of U(VI) and Pu(IV) does not occur. The procedures of vacuum distillation and overheated steam stripping are described for regeneration of Polysorb-1 sorbent containing TBP and HCBD. The optimal process temperature was chosen to be 170°C.
期刊介绍：
Radiochemistry is a journal that covers the theoretical and applied aspects of radiochemistry, including basic nuclear physical properties of radionuclides; chemistry of radioactive elements and their compounds; the occurrence and behavior of natural and artificial radionuclides in the environment; nuclear fuel cycle; radiochemical analysis methods and devices; production and isolation of radionuclides, synthesis of labeled compounds, new applications of radioactive tracers; radiochemical aspects of nuclear medicine; radiation chemistry and after-effects of nuclear transformations.
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