{"title":"掺杂 Yb3+ 的 Cs2NaScF6 单晶的合成和掺杂 Yb3+ 离子的 EPR 光谱分析","authors":"M. L. Falin, V. A. Latypov, N. M. Khaidukov","doi":"10.1007/s00723-024-01656-w","DOIUrl":null,"url":null,"abstract":"<div><p>Single crystals of Yb<sup>3+</sup>-doped Cs<sub>2</sub>NaScF<sub>6</sub> are synthesized under hydrothermal conditions and dopant Yb<sup>3+</sup> ions are studied using electron paramagnetic resonance spectroscopy. The paramagnetic Yb<sup>3+</sup> center of cubic symmetry is detected. The parameters of the corresponding spin Hamiltonians and the ground state Г<sub>6</sub> are determined. A structural model of the complex under study is proposed. The experimental results are analyzed by comparison with those for the paramagnetic Yb<sup>3+</sup> ion in other lattices.</p></div>","PeriodicalId":469,"journal":{"name":"Applied Magnetic Resonance","volume":"55 9","pages":"1129 - 1135"},"PeriodicalIF":1.1000,"publicationDate":"2024-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis of Yb3+-Doped Cs2NaScF6 Single Crystals and EPR Spectroscopy of the Dopant Yb3+ ion\",\"authors\":\"M. L. Falin, V. A. Latypov, N. M. Khaidukov\",\"doi\":\"10.1007/s00723-024-01656-w\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Single crystals of Yb<sup>3+</sup>-doped Cs<sub>2</sub>NaScF<sub>6</sub> are synthesized under hydrothermal conditions and dopant Yb<sup>3+</sup> ions are studied using electron paramagnetic resonance spectroscopy. The paramagnetic Yb<sup>3+</sup> center of cubic symmetry is detected. The parameters of the corresponding spin Hamiltonians and the ground state Г<sub>6</sub> are determined. A structural model of the complex under study is proposed. The experimental results are analyzed by comparison with those for the paramagnetic Yb<sup>3+</sup> ion in other lattices.</p></div>\",\"PeriodicalId\":469,\"journal\":{\"name\":\"Applied Magnetic Resonance\",\"volume\":\"55 9\",\"pages\":\"1129 - 1135\"},\"PeriodicalIF\":1.1000,\"publicationDate\":\"2024-04-30\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Applied Magnetic Resonance\",\"FirstCategoryId\":\"101\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s00723-024-01656-w\",\"RegionNum\":4,\"RegionCategory\":\"物理与天体物理\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"PHYSICS, ATOMIC, MOLECULAR & CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Applied Magnetic Resonance","FirstCategoryId":"101","ListUrlMain":"https://link.springer.com/article/10.1007/s00723-024-01656-w","RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"PHYSICS, ATOMIC, MOLECULAR & CHEMICAL","Score":null,"Total":0}
Synthesis of Yb3+-Doped Cs2NaScF6 Single Crystals and EPR Spectroscopy of the Dopant Yb3+ ion
Single crystals of Yb3+-doped Cs2NaScF6 are synthesized under hydrothermal conditions and dopant Yb3+ ions are studied using electron paramagnetic resonance spectroscopy. The paramagnetic Yb3+ center of cubic symmetry is detected. The parameters of the corresponding spin Hamiltonians and the ground state Г6 are determined. A structural model of the complex under study is proposed. The experimental results are analyzed by comparison with those for the paramagnetic Yb3+ ion in other lattices.
期刊介绍：
Applied Magnetic Resonance provides an international forum for the application of magnetic resonance in physics, chemistry, biology, medicine, geochemistry, ecology, engineering, and related fields.
The contents include articles with a strong emphasis on new applications, and on new experimental methods. Additional features include book reviews and Letters to the Editor.
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