掺杂 Yb3+ 的 Cs2NaScF6 单晶的合成和掺杂 Yb3+ 离子的 EPR 光谱分析

IF 1.1 4区 物理与天体物理 Q4 PHYSICS, ATOMIC, MOLECULAR & CHEMICAL Applied Magnetic Resonance Pub Date : 2024-04-30 DOI:10.1007/s00723-024-01656-w
M. L. Falin, V. A. Latypov, N. M. Khaidukov
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引用次数: 0

摘要

在水热条件下合成了掺杂 Yb3+ 的 Cs2NaScF6 单晶体,并利用电子顺磁共振光谱对掺杂的 Yb3+ 离子进行了研究。检测到了立方对称的顺磁 Yb3+ 中心。确定了相应的自旋哈密顿参数和基态 Г6。提出了所研究复合物的结构模型。通过与其他晶格中顺磁性 Yb3+ 离子的实验结果进行比较,对实验结果进行了分析。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Synthesis of Yb3+-Doped Cs2NaScF6 Single Crystals and EPR Spectroscopy of the Dopant Yb3+ ion

Single crystals of Yb3+-doped Cs2NaScF6 are synthesized under hydrothermal conditions and dopant Yb3+ ions are studied using electron paramagnetic resonance spectroscopy. The paramagnetic Yb3+ center of cubic symmetry is detected. The parameters of the corresponding spin Hamiltonians and the ground state Г6 are determined. A structural model of the complex under study is proposed. The experimental results are analyzed by comparison with those for the paramagnetic Yb3+ ion in other lattices.

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来源期刊
Applied Magnetic Resonance
Applied Magnetic Resonance 物理-光谱学
CiteScore
1.90
自引率
10.00%
发文量
59
审稿时长
2.3 months
期刊介绍: Applied Magnetic Resonance provides an international forum for the application of magnetic resonance in physics, chemistry, biology, medicine, geochemistry, ecology, engineering, and related fields. The contents include articles with a strong emphasis on new applications, and on new experimental methods. Additional features include book reviews and Letters to the Editor.
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