{"title":"肼基茚基硫酸锌和硒酸锌 (EMSFluind)2 (E = S, Se)","authors":"Jens Beckmann, Pascal Komorr, Pim Puylaert","doi":"10.1002/zaac.202400052","DOIUrl":null,"url":null,"abstract":"The bulky aryl thiol, MSFluindSH (1S), and aryl selenol, MSFluindSeH (1Se), possessing a tetramethyl‐s‐hydrindacen‐4’‐yl‐(Rind)‐based substituent containing two fluorenyl groups in 9 and 9’‐positions, were prepared (MSFluind = dispiro[fluorene‐9,3’‐(1’,1’,7’,7’‐tetramethyl‐s‐hydrindacene‐4’‐yl)‐5’,9’’‐fluorene]). The reaction of 1S and 1Se with Et2Zn provided a monomeric zinc aryl thiolate, Zn(SMSFluind)2 (2S), and zinc aryl selenolate, Zn(SeMSFluind)2 (2Se), with essentially two‐coordinate zinc atoms.","PeriodicalId":23934,"journal":{"name":"Zeitschrift für anorganische und allgemeine Chemie","volume":"2012 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-05-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Hydrindacene‐Based Zinc Aryl Thiolate and Aryl Selenolate Zn(EMSFluind)2 (E = S, Se)\",\"authors\":\"Jens Beckmann, Pascal Komorr, Pim Puylaert\",\"doi\":\"10.1002/zaac.202400052\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The bulky aryl thiol, MSFluindSH (1S), and aryl selenol, MSFluindSeH (1Se), possessing a tetramethyl‐s‐hydrindacen‐4’‐yl‐(Rind)‐based substituent containing two fluorenyl groups in 9 and 9’‐positions, were prepared (MSFluind = dispiro[fluorene‐9,3’‐(1’,1’,7’,7’‐tetramethyl‐s‐hydrindacene‐4’‐yl)‐5’,9’’‐fluorene]). The reaction of 1S and 1Se with Et2Zn provided a monomeric zinc aryl thiolate, Zn(SMSFluind)2 (2S), and zinc aryl selenolate, Zn(SeMSFluind)2 (2Se), with essentially two‐coordinate zinc atoms.\",\"PeriodicalId\":23934,\"journal\":{\"name\":\"Zeitschrift für anorganische und allgemeine Chemie\",\"volume\":\"2012 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-05-02\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Zeitschrift für anorganische und allgemeine Chemie\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1002/zaac.202400052\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Zeitschrift für anorganische und allgemeine Chemie","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1002/zaac.202400052","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Hydrindacene‐Based Zinc Aryl Thiolate and Aryl Selenolate Zn(EMSFluind)2 (E = S, Se)
The bulky aryl thiol, MSFluindSH (1S), and aryl selenol, MSFluindSeH (1Se), possessing a tetramethyl‐s‐hydrindacen‐4’‐yl‐(Rind)‐based substituent containing two fluorenyl groups in 9 and 9’‐positions, were prepared (MSFluind = dispiro[fluorene‐9,3’‐(1’,1’,7’,7’‐tetramethyl‐s‐hydrindacene‐4’‐yl)‐5’,9’’‐fluorene]). The reaction of 1S and 1Se with Et2Zn provided a monomeric zinc aryl thiolate, Zn(SMSFluind)2 (2S), and zinc aryl selenolate, Zn(SeMSFluind)2 (2Se), with essentially two‐coordinate zinc atoms.
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