确定东南印度洋稳定氧同位素组成的特征

IF 3 3区 地球科学 Q2 CHEMISTRY, MULTIDISCIPLINARY Marine Chemistry Pub Date : 2024-05-01 DOI:10.1016/j.marchem.2024.104397
Ryan H. Glaubke , Amy J. Wagner , Elisabeth L. Sikes
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引用次数: 0

摘要

2018年11月至12月,作为 "CROCCA-2S"(Coring to Reconstruct Ocean Circulation and Carbon dioxide Across 2 Seas)考察的一部分,从印度洋东南部采集了新的海水稳定氧同位素(δ18O)样本。这些数据填补了南印度洋海盆δ18O取样覆盖范围的空白,为了解影响该区域δ18O分布的水文和海洋学过程及其与上层海洋盐度的关系提供了新的视角。我们的表层海洋数据(<100 m)--结合几十年来对更广阔的南印度洋的观测--显示出在∼85°E 两侧不同的 δ18O - 盐度特征。蒸发和降水之间的平衡在东经 85 度以西产生了强烈的δ18O-盐度关系(δ18O = 0.50(±0.01) * S - 17.2(±0.22))。然而,在更东面(∼85-120°E)由卢温洋流(Leeuwin Current)引发的中尺度涡场中,我们的观测结果位于西南印度洋与澳大利亚沿岸边缘数据之间的混合线上,首次说明了南印度洋独特的东部边界系统如何驱动表层海洋δ18O-盐度关系的区域尺度变化。我们在浅层次表层(100-1000 米)的观测结果与邻近地区的观测结果进行了比较,从而加强了整个印度洋-澳大利亚海盆上层海洋的联系。来自印度洋的南极中层水在同位素上可以与占据南澳大利亚海湾的更具区域性的塔斯曼中层水区分开来,这表明两个区域之间的交换在表层和模式水深最为普遍。在更深的水域(> ∼ 1500 米),我们观察到 δ18O 有明显的 0.87‰的差异。这种变化可能代表了该区域不同深水水团之间的相互作用,但还需要更多的数据来证实。总之,我们的数据为东南印度洋的水文地理和同位素化学提供了一个新的视角,强调了该地区中尺度涡场的影响及其与邻近盆地的相互联系。
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Characterizing the stable oxygen isotopic composition of the southeast Indian Ocean

New seawater stable oxygen isotope (δ18O) samples were collected from the southeast Indian Ocean as part of the Coring to Reconstruct Ocean Circulation and Carbon dioxide Across 2 Seas (CROCCA-2S) expedition in November – December of 2018. These data fill a gap in the δ18O sampling coverage of the southern Indian basin, providing new insights into the hydrologic and oceanographic processes influencing the δ18O distribution of the region and its relationship to salinity in the upper ocean. Our surface ocean data (<100 m)—in combination with decades of observations from the broader south Indian Ocean—show distinct δ18O – salinity characteristics on either side of ∼85°E. The balance between evaporation and precipitation yields a strong, robust δ18O – salinity relationship west of 85°E (δ18O = 0.50(±0.01) * S – 17.2(±0.22)). However, within the mesoscale eddy field initiated by the Leeuwin Current further east (∼85–120°E), our observations fall along a mixing line between the southwest Indian Ocean and data collected from the Australian coastal margin, illustrating for the first time how the unique eastern boundary system of the south Indian Ocean drives regional-scale variability in the δ18O – salinity relationship of the surface ocean. A comparison between our observations in the shallow subsurface (100–1000 m) and those from neighboring surveys reinforces this upper ocean connection across the Indo-Australian basin. Antarctic Intermediate Water from the Indian Ocean can be isotopically distinguished from the more regional Tasman Intermediate Water occupying the South Australian Bight, suggesting exchange between the two regions is most prevalent at surface and mode water depths. In deeper waters (> ∼1500 m), we observe a notable 0.87‰ spread in δ18O. This variability may represent interactions between distinct deep water masses in the region, although additional data are needed to confirm. Overall, our data provide a new look at the hydrography and isotopic chemistry of the southeast Indian Ocean, emphasizing the impact of the region's mesoscale eddy field and its interconnectivity with neighboring basins.

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来源期刊
Marine Chemistry
Marine Chemistry 化学-海洋学
CiteScore
6.00
自引率
3.30%
发文量
70
审稿时长
4.5 months
期刊介绍: Marine Chemistry is an international medium for the publication of original studies and occasional reviews in the field of chemistry in the marine environment, with emphasis on the dynamic approach. The journal endeavours to cover all aspects, from chemical processes to theoretical and experimental work, and, by providing a central channel of communication, to speed the flow of information in this relatively new and rapidly expanding discipline.
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