用于固化累积碱性高放废物溶液部分的前景看好的干混配方

IF 0.9 Q4 CHEMISTRY, INORGANIC & NUCLEAR Radiochemistry Pub Date : 2024-03-12 DOI:10.1134/S1066362223070068
P. V. Kozlov, S. M. Shaidullin, K. A. Feoktistov, D. V. Markova, R. Ya. Akhtyamov, R. M. Akhmed’yanov
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引用次数: 0

摘要

摘要 研究了在开发马雅克生产协会积累的碱性高放射性废物(HLW)溶液部分固化工艺过程中制备的水泥砂浆和化合物。干混配方中只使用了俄罗斯市场上销售的材料。测定了模型非活性水泥砂浆的铺展、渗水、终凝和放热情况,以及化合物的抗压强度、抗冻性和耐水性。用真实凝固的高浓度溶液测定了水泥化合物的 137Cs 浸出率。开发出了符合固结放射性废物的整套法规和技术要求的配方,前提是将化合物置于有限容积的容器(如 NZK 型容器)中。
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Promising Dry Mix Formulations for Cementation of the Solution Fraction of the Accumulated Alkaline High-Level Waste

Cement mortars and compounds prepared in the course of the development of a process for solidification of the solution fraction of alkaline high-level waste (HLW) accumulated at the Mayak Production Association were studied. Only materials commercially available in Russia were included in dry mix formulations. The spread, bleeding, final setting, and heat release were determined for model inactive cement mortars, and the compression strength, frost resistance, and water resistance, for the compounds. The 137Cs leach rate was determined for the cement compounds with real solidified high-level solutions. The formulation meeting the whole set of regulatory and technological requirements to cemented radioactive waste, provided that the compound is placed in limited-volume containers (e.g., in NZK-type containers), was developed.

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来源期刊
Radiochemistry
Radiochemistry CHEMISTRY, INORGANIC & NUCLEAR-
CiteScore
1.30
自引率
33.30%
发文量
51
期刊介绍: Radiochemistry  is a journal that covers the theoretical and applied aspects of radiochemistry, including basic nuclear physical properties of radionuclides; chemistry of radioactive elements and their compounds; the occurrence and behavior of natural and artificial radionuclides in the environment; nuclear fuel cycle; radiochemical analysis methods and devices; production and isolation of radionuclides, synthesis of labeled compounds, new applications of radioactive tracers; radiochemical aspects of nuclear medicine; radiation chemistry and after-effects of nuclear transformations.
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