{"title":"基于 Y 型配体的新型 Ni(II) 配位聚合物的水热合成与结构表征","authors":"H. X. Kang, Y. Q. Fu, G. Z. Liu","doi":"10.1134/s1063774522100133","DOIUrl":null,"url":null,"abstract":"<h3 data-test=\"abstract-sub-heading\">Abstract</h3><p>A novel Y-shaped ligand 2,2'-(5-((1H-1,2,4-triazol-1-yl)methyl)-1,3-phenylene)bis(2-methyl propionic acid) (H<sub>2</sub>L) and its Ni(II) coordination polymer were synthesized under appropriate conditions. Their structures were characterized by single-crystal X-ray diffraction and other physicochemical techniques. The Ni(II) coordination polymer shows an infinite 1D cage structure along the <i>a</i> direction.</p>","PeriodicalId":527,"journal":{"name":"Crystallography Reports","volume":null,"pages":null},"PeriodicalIF":0.6000,"publicationDate":"2024-02-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Hydrothermal Synthesis and Structural Characterization of a Novel Ni(II) Coordination Polymer Based on a Y-shaped Ligand\",\"authors\":\"H. X. Kang, Y. Q. Fu, G. Z. Liu\",\"doi\":\"10.1134/s1063774522100133\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<h3 data-test=\\\"abstract-sub-heading\\\">Abstract</h3><p>A novel Y-shaped ligand 2,2'-(5-((1H-1,2,4-triazol-1-yl)methyl)-1,3-phenylene)bis(2-methyl propionic acid) (H<sub>2</sub>L) and its Ni(II) coordination polymer were synthesized under appropriate conditions. Their structures were characterized by single-crystal X-ray diffraction and other physicochemical techniques. The Ni(II) coordination polymer shows an infinite 1D cage structure along the <i>a</i> direction.</p>\",\"PeriodicalId\":527,\"journal\":{\"name\":\"Crystallography Reports\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.6000,\"publicationDate\":\"2024-02-06\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Crystallography Reports\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1134/s1063774522100133\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CRYSTALLOGRAPHY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Crystallography Reports","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1134/s1063774522100133","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CRYSTALLOGRAPHY","Score":null,"Total":0}
引用次数: 0
摘要
摘要 在适当条件下合成了一种新型 Y 型配体 2,2'-(5-((1H-1,2,4-三唑-1-基)甲基)-1,3-亚苯基)双(2-甲基丙酸)(H2L)及其 Ni(II) 配位聚合物。通过单晶 X 射线衍射和其他理化技术对它们的结构进行了表征。Ni(II)配位聚合物沿 a 方向呈现出无限的一维笼状结构。
Hydrothermal Synthesis and Structural Characterization of a Novel Ni(II) Coordination Polymer Based on a Y-shaped Ligand
Abstract
A novel Y-shaped ligand 2,2'-(5-((1H-1,2,4-triazol-1-yl)methyl)-1,3-phenylene)bis(2-methyl propionic acid) (H2L) and its Ni(II) coordination polymer were synthesized under appropriate conditions. Their structures were characterized by single-crystal X-ray diffraction and other physicochemical techniques. The Ni(II) coordination polymer shows an infinite 1D cage structure along the a direction.
期刊介绍:
Crystallography Reports is a journal that publishes original articles short communications, and reviews on various aspects of crystallography: diffraction and scattering of X-rays, electrons, and neutrons, determination of crystal structure of inorganic and organic substances, including proteins and other biological substances; UV-VIS and IR spectroscopy; growth, imperfect structure and physical properties of crystals; thin films, liquid crystals, nanomaterials, partially disordered systems, and the methods of studies.