Danielle Hilhorst , Seung-Min Kang , Ho-Youn Kim , Yong-Jung Kim
{"title":"菲克定律选择诺依曼边界条件","authors":"Danielle Hilhorst , Seung-Min Kang , Ho-Youn Kim , Yong-Jung Kim","doi":"10.1016/j.na.2024.113561","DOIUrl":null,"url":null,"abstract":"<div><p>We show that the Neumann boundary condition appears along the boundary of an inner domain when the diffusivity of the outer domain goes to zero. We take Fick’s diffusion law with a bistable reaction function, and the diffusivity is 1 in the inner domain and <span><math><mrow><mi>ϵ</mi><mo>></mo><mn>0</mn></mrow></math></span> in the outer domain. The convergence of the solution as <span><math><mrow><mi>ϵ</mi><mo>→</mo><mn>0</mn></mrow></math></span> is shown, where the limit satisfies the Neumann boundary condition along the boundary of an inner domain. This observation says that the Neumann boundary condition is a natural choice of boundary conditions when Fick’s diffusion law is taken.</p></div>","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":null,"pages":null},"PeriodicalIF":16.4000,"publicationDate":"2024-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Fick’s law selects the Neumann boundary condition\",\"authors\":\"Danielle Hilhorst , Seung-Min Kang , Ho-Youn Kim , Yong-Jung Kim\",\"doi\":\"10.1016/j.na.2024.113561\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>We show that the Neumann boundary condition appears along the boundary of an inner domain when the diffusivity of the outer domain goes to zero. We take Fick’s diffusion law with a bistable reaction function, and the diffusivity is 1 in the inner domain and <span><math><mrow><mi>ϵ</mi><mo>></mo><mn>0</mn></mrow></math></span> in the outer domain. The convergence of the solution as <span><math><mrow><mi>ϵ</mi><mo>→</mo><mn>0</mn></mrow></math></span> is shown, where the limit satisfies the Neumann boundary condition along the boundary of an inner domain. This observation says that the Neumann boundary condition is a natural choice of boundary conditions when Fick’s diffusion law is taken.</p></div>\",\"PeriodicalId\":1,\"journal\":{\"name\":\"Accounts of Chemical Research\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":16.4000,\"publicationDate\":\"2024-05-13\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Accounts of Chemical Research\",\"FirstCategoryId\":\"100\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0362546X24000804\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"100","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0362546X24000804","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
We show that the Neumann boundary condition appears along the boundary of an inner domain when the diffusivity of the outer domain goes to zero. We take Fick’s diffusion law with a bistable reaction function, and the diffusivity is 1 in the inner domain and in the outer domain. The convergence of the solution as is shown, where the limit satisfies the Neumann boundary condition along the boundary of an inner domain. This observation says that the Neumann boundary condition is a natural choice of boundary conditions when Fick’s diffusion law is taken.
期刊介绍:
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.