首次全合成阿斯佩里内酯 B。修订阿斯佩里内酯 B 和 C 的绝对立体化学。

IF 2.7 3区 化学 Q1 CHEMISTRY, ORGANIC Organic & Biomolecular Chemistry Pub Date : 2024-06-19 Epub Date: 2024-05-10 DOI:10.1039/d4ob00583j
Sanja Djokić , Goran Benedeković , Jelena Kesić , Marko V. Rodić , Mirjana Popsavin , Velimir Popsavin , Jovana Francuz
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引用次数: 0

摘要

首次完成了阿斯佩里内酯 B (I) 的全合成和绝对构型分配。此外,还对阿斯佩里内酯 C 的绝对立体化学进行了修订。此外,还首次合成了阿斯佩里内酯 B 的对映体(ent-I),以及阿斯佩里内酯 B (8) 和 C (9) 的 C-7 外比体。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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First total synthesis of asperilactone B. Revision of absolute stereochemistry of asperilactones B and C†

The first total synthesis and absolute configuration assignment of asperilactone B (I) have been accomplished. Additionally, a revision of the absolute stereochemistry of asperilactone C has been done. The first total synthesis of the opposite enantiomer of asperilactone B (ent-I) has also been achieved, as well as that of C-7 epimers of both asperilactones B (8) and C (9).

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来源期刊
Organic & Biomolecular Chemistry
Organic & Biomolecular Chemistry 化学-有机化学
CiteScore
5.50
自引率
9.40%
发文量
1056
审稿时长
1.3 months
期刊介绍: Organic & Biomolecular Chemistry is an international journal using integrated research in chemistry-organic chemistry. Founded in 2003 by the Royal Society of Chemistry, the journal is published in Semimonthly issues and has been indexed by SCIE, a leading international database. The journal focuses on the key research and cutting-edge progress in the field of chemistry-organic chemistry, publishes and reports the research results in this field in a timely manner, and is committed to becoming a window and platform for rapid academic exchanges among peers in this field. The journal's impact factor in 2023 is 2.9, and its CiteScore is 5.5.
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