作为双光子聚合引发剂的 N,N-二乙基-4-(苯基二氮)苯胺的甲基丙烯酸酯-С-含对衍生物

IF 0.9 4区化学 Q4 CHEMISTRY, PHYSICAL High Energy Chemistry Pub Date : 2024-05-13 DOI:10.1134/s0018143924700115

M. V. Arsenyev, E. R. Zhiganshina, D. A. Kolymagin, V. A. Ilyichev, R. S. Kovylin, A. G. Vitukhnovsky, S. A. Chesnokov

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引用次数: 0

摘要

摘要研究考虑了使用一系列相对于偶氮基团具有不同对位取代基（-H、-Br、-NO2）的含甲基丙烯酸酯的 N,N-二乙基-4-（苯基二氮基）苯胺作为自由基聚合的光引发剂的可能性。对这些化合物的电化学和光致发光特性进行了研究。在偶氮染料存在的情况下，使用飞秒激光器发出的 780 纳米聚焦辐射对季戊四醇三丙烯酸酯进行了双光子光聚合反应。通过 DLW 纳米光刻技术获得了线性元素最小尺寸为 94 ± 5 nm 的结构，并制造出了结构复杂的三维微结构。

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Methacrylate-Сontaining Para-Derivatives of N,N-Diethyl-4-(phenyldiazenyl)aniline as Initiators in Two-Photon Polymerization

Abstract

The possibility of using a series of methacrylate-containing N,N-diethyl-4-(phenyldiazenyl)anilines with various para-substituents (–H, –Br, –NO₂) relative to the azo group as photoinitiators of radical polymerization is considered. The electrochemical and photoluminescent properties of these compounds have been studied. In the presence of azo dyes, two-photon photopolymerization of pentaerythritol triacrylate was carried out using focused 780-nm radiation from a femtosecond laser. Structures with minimal dimensions of linear elements of 94 ± 5 nm were obtained by means of the DLW nanolithography technique, and 3D microstructures of complex architecture were fabricated.

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来源期刊

High Energy Chemistry 化学-物理化学

CiteScore

1.50

自引率

28.60%

发文量

审稿时长

6-12 weeks

期刊介绍： High Energy Chemistry publishes original articles, reviews, and short communications on molecular and supramolecular photochemistry, photobiology, radiation chemistry, plasma chemistry, chemistry of nanosized systems, chemistry of new atoms, processes and materials for optical information systems and other areas of high energy chemistry. It publishes theoretical and experimental studies in all areas of high energy chemistry, such as the interaction of high-energy particles with matter, the nature and reactivity of short-lived species induced by the action of particle and electromagnetic radiation or hot atoms on substances in their gaseous and condensed states, and chemical processes initiated in organic and inorganic systems by high-energy radiation.