{"title":"通过与 Sr2Bi4Ti5O18 和 ZnSnO3 氧化物形成固溶体增强 YFeO3 陶瓷的磁性和介电特性","authors":"Kolleti Venkatadri, Dudekula Zarena","doi":"10.1002/pssb.202400089","DOIUrl":null,"url":null,"abstract":"In the present investigation, magnetic and dielectric properties of solid‐solution formed between the YFeO<jats:sub>3</jats:sub> with the similar crystal structure of other oxide materials are focused on. Orthorhombic crystal structure of YFeO<jats:sub>3</jats:sub> (YFO), Sr<jats:sub>2</jats:sub>Bi<jats:sub>4</jats:sub>Ti<jats:sub>5</jats:sub>O<jats:sub>18</jats:sub> (SBT), and ZnSnO<jats:sub>3</jats:sub> (ZS) nanomaterials are considered to prepare the solid solutions at 1150 °C/3 h. YFO and solid solutions exhibit the orthorhombic crystal structure, which is conformed through Rietveld refinement using X‐Ray powder diffraction pattern. The decreased average grain size is observed for the solid solution (3.0 μm for YFO and ZS and 2.6 μm for YFO and SBT) when compared to YFO (3.4 μm) through scanning electron microscopy. Oxidation state of each atom/ion/element present in the YFO and solid solutions are conformed through X‐Ray photoelectron spectroscopy studies. The solid solution formed between the YFO and SBT exhibits high magnetization value (2.92 emu g<jats:sup>−1</jats:sup>) and high coercive filed (67.5 Oe) when compared to solid solution formed between the YFO and ZS (magnetization value = 2.48 emu g<jats:sup>−1</jats:sup>, and coercive filed = 46.4 Oe) and YFO (magnetization value = 1.91 emu g<jats:sup>−1</jats:sup>, and coercive filed = 61.8 Oe). High dielectric permittivity (<jats:italic>ε</jats:italic><jats:sub>r</jats:sub>), low dielectric loss (tan <jats:italic>δ</jats:italic>), and low conductivity are observed for the solid solution formed between the YFO and SBT, when compared to other materials in this study.","PeriodicalId":20406,"journal":{"name":"Physica Status Solidi B-basic Solid State Physics","volume":null,"pages":null},"PeriodicalIF":1.5000,"publicationDate":"2024-05-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Enhanced Magnetic and Dielectric Properties of YFeO3 Ceramics via Formation of Solid‐Solution with Sr2Bi4Ti5O18 and ZnSnO3 Oxides\",\"authors\":\"Kolleti Venkatadri, Dudekula Zarena\",\"doi\":\"10.1002/pssb.202400089\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"In the present investigation, magnetic and dielectric properties of solid‐solution formed between the YFeO<jats:sub>3</jats:sub> with the similar crystal structure of other oxide materials are focused on. Orthorhombic crystal structure of YFeO<jats:sub>3</jats:sub> (YFO), Sr<jats:sub>2</jats:sub>Bi<jats:sub>4</jats:sub>Ti<jats:sub>5</jats:sub>O<jats:sub>18</jats:sub> (SBT), and ZnSnO<jats:sub>3</jats:sub> (ZS) nanomaterials are considered to prepare the solid solutions at 1150 °C/3 h. YFO and solid solutions exhibit the orthorhombic crystal structure, which is conformed through Rietveld refinement using X‐Ray powder diffraction pattern. The decreased average grain size is observed for the solid solution (3.0 μm for YFO and ZS and 2.6 μm for YFO and SBT) when compared to YFO (3.4 μm) through scanning electron microscopy. Oxidation state of each atom/ion/element present in the YFO and solid solutions are conformed through X‐Ray photoelectron spectroscopy studies. The solid solution formed between the YFO and SBT exhibits high magnetization value (2.92 emu g<jats:sup>−1</jats:sup>) and high coercive filed (67.5 Oe) when compared to solid solution formed between the YFO and ZS (magnetization value = 2.48 emu g<jats:sup>−1</jats:sup>, and coercive filed = 46.4 Oe) and YFO (magnetization value = 1.91 emu g<jats:sup>−1</jats:sup>, and coercive filed = 61.8 Oe). High dielectric permittivity (<jats:italic>ε</jats:italic><jats:sub>r</jats:sub>), low dielectric loss (tan <jats:italic>δ</jats:italic>), and low conductivity are observed for the solid solution formed between the YFO and SBT, when compared to other materials in this study.\",\"PeriodicalId\":20406,\"journal\":{\"name\":\"Physica Status Solidi B-basic Solid State Physics\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.5000,\"publicationDate\":\"2024-05-12\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Physica Status Solidi B-basic Solid State Physics\",\"FirstCategoryId\":\"101\",\"ListUrlMain\":\"https://doi.org/10.1002/pssb.202400089\",\"RegionNum\":4,\"RegionCategory\":\"物理与天体物理\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"PHYSICS, CONDENSED MATTER\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Physica Status Solidi B-basic Solid State Physics","FirstCategoryId":"101","ListUrlMain":"https://doi.org/10.1002/pssb.202400089","RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"PHYSICS, CONDENSED MATTER","Score":null,"Total":0}
Enhanced Magnetic and Dielectric Properties of YFeO3 Ceramics via Formation of Solid‐Solution with Sr2Bi4Ti5O18 and ZnSnO3 Oxides
In the present investigation, magnetic and dielectric properties of solid‐solution formed between the YFeO3 with the similar crystal structure of other oxide materials are focused on. Orthorhombic crystal structure of YFeO3 (YFO), Sr2Bi4Ti5O18 (SBT), and ZnSnO3 (ZS) nanomaterials are considered to prepare the solid solutions at 1150 °C/3 h. YFO and solid solutions exhibit the orthorhombic crystal structure, which is conformed through Rietveld refinement using X‐Ray powder diffraction pattern. The decreased average grain size is observed for the solid solution (3.0 μm for YFO and ZS and 2.6 μm for YFO and SBT) when compared to YFO (3.4 μm) through scanning electron microscopy. Oxidation state of each atom/ion/element present in the YFO and solid solutions are conformed through X‐Ray photoelectron spectroscopy studies. The solid solution formed between the YFO and SBT exhibits high magnetization value (2.92 emu g−1) and high coercive filed (67.5 Oe) when compared to solid solution formed between the YFO and ZS (magnetization value = 2.48 emu g−1, and coercive filed = 46.4 Oe) and YFO (magnetization value = 1.91 emu g−1, and coercive filed = 61.8 Oe). High dielectric permittivity (εr), low dielectric loss (tan δ), and low conductivity are observed for the solid solution formed between the YFO and SBT, when compared to other materials in this study.
期刊介绍:
physica status solidi is devoted to the thorough peer review and the rapid publication of new and important results in all fields of solid state and materials physics, from basic science to applications and devices. Being among the largest and most important international publications, the pss journals publish review articles, letters and original work as well as special issues and conference contributions.
physica status solidi b – basic solid state physics is devoted to topics such as theoretical and experimental investigations of the atomistic and electronic structure of solids in general, phase transitions, electronic and optical properties of low-dimensional, nano-scale, strongly correlated, or disordered systems, superconductivity, magnetism, ferroelectricity etc.