{"title":"303.15 K 时四元体系 KCl-KH2PO4-(NH2)2CO-H2O 及其三元子体系 KH2PO4-(NH2)2CO-H2O 的固液平衡的测量与相关性","authors":"Feng Yi, Jing Zhu, Linrui Zhong, Tianxiang Li* and Songlin Liu*, ","doi":"10.1021/acs.jced.3c00751","DOIUrl":null,"url":null,"abstract":"<p >The phase equilibria of the quaternary system KCl–KH<sub>2</sub>PO<sub>4</sub>–(NH<sub>2</sub>)<sub>2</sub>CO–H<sub>2</sub>O and its ternary subsystem KH<sub>2</sub>PO<sub>4</sub>–(NH<sub>2</sub>)<sub>2</sub>CO–H<sub>2</sub>O at 303.15 K were studied by the isothermal dissolution equilibrium method, and the phase diagrams were plotted. The equilibrium solid phase was identified by Schreinemaker’s wet residue method and X-ray diffraction (XRD). The ternary subsystem is a simple cosaturated system, the phase diagram contains one saturation point, two univariate curves, and three crystallization regions. A comparison of the phase diagrams of ternary subsystem at different temperatures shows that the cocrystallization region of KH<sub>2</sub>PO<sub>4</sub> and (NH<sub>2</sub>)<sub>2</sub>CO decreases with the increase of temperature. The phase diagram of the quaternary system shows that the system is a simple cosaturated system, including one invariant point, three univariant curves, and three crystallization regions. Based on the Pitzer–H–W model, the lacking particle interaction parameters were regressed using the solubility data of the ternary systems and used to calculate the solubility data. By comparing the experimental value with the calculated value, the results both indicated that the experiment and theoretical calculation have good consistency, and the Pitzer–H–W model is suitable for the electrolyte and neutral molecule solution systems.</p>","PeriodicalId":42,"journal":{"name":"Journal of Chemical & Engineering Data","volume":null,"pages":null},"PeriodicalIF":2.0000,"publicationDate":"2024-05-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Measurement and Correlation of Solid–Liquid Equilibria of Quaternary System KCl–KH2PO4–(NH2)2CO–H2O and Its Ternary Subsystem KH2PO4–(NH2)2CO–H2O at 303.15 K\",\"authors\":\"Feng Yi, Jing Zhu, Linrui Zhong, Tianxiang Li* and Songlin Liu*, \",\"doi\":\"10.1021/acs.jced.3c00751\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >The phase equilibria of the quaternary system KCl–KH<sub>2</sub>PO<sub>4</sub>–(NH<sub>2</sub>)<sub>2</sub>CO–H<sub>2</sub>O and its ternary subsystem KH<sub>2</sub>PO<sub>4</sub>–(NH<sub>2</sub>)<sub>2</sub>CO–H<sub>2</sub>O at 303.15 K were studied by the isothermal dissolution equilibrium method, and the phase diagrams were plotted. The equilibrium solid phase was identified by Schreinemaker’s wet residue method and X-ray diffraction (XRD). The ternary subsystem is a simple cosaturated system, the phase diagram contains one saturation point, two univariate curves, and three crystallization regions. A comparison of the phase diagrams of ternary subsystem at different temperatures shows that the cocrystallization region of KH<sub>2</sub>PO<sub>4</sub> and (NH<sub>2</sub>)<sub>2</sub>CO decreases with the increase of temperature. The phase diagram of the quaternary system shows that the system is a simple cosaturated system, including one invariant point, three univariant curves, and three crystallization regions. Based on the Pitzer–H–W model, the lacking particle interaction parameters were regressed using the solubility data of the ternary systems and used to calculate the solubility data. By comparing the experimental value with the calculated value, the results both indicated that the experiment and theoretical calculation have good consistency, and the Pitzer–H–W model is suitable for the electrolyte and neutral molecule solution systems.</p>\",\"PeriodicalId\":42,\"journal\":{\"name\":\"Journal of Chemical & Engineering Data\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.0000,\"publicationDate\":\"2024-05-08\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Chemical & Engineering Data\",\"FirstCategoryId\":\"1\",\"ListUrlMain\":\"https://pubs.acs.org/doi/10.1021/acs.jced.3c00751\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Chemical & Engineering Data","FirstCategoryId":"1","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acs.jced.3c00751","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
摘要
采用等温溶解平衡法研究了 303.15 K 下四元体系 KCl-KH2PO4-(NH2)2CO-H2O 及其三元子体系 KH2PO4-(NH2)2CO-H2O 的相平衡,并绘制了相图。用 Schreinemaker 湿残留法和 X 射线衍射 (XRD) 鉴定了平衡固相。三元子系统是一个简单的共饱和系统,相图包含一个饱和点、两条单变量曲线和三个结晶区。不同温度下三元子系统相图的比较表明,KH2PO4 和 (NH2)2CO 的共晶区随着温度的升高而减小。四元体系的相图显示,该体系是一个简单的共饱和体系,包括一个不变点、三条单变量曲线和三个结晶区。根据 Pitzer-H-W 模型,利用三元体系的溶解度数据对缺乏的粒子相互作用参数进行回归,并用于计算溶解度数据。通过比较实验值和计算值,结果表明实验和理论计算具有良好的一致性,Pitzer-H-W 模型适用于电解质和中性分子溶液体系。
Measurement and Correlation of Solid–Liquid Equilibria of Quaternary System KCl–KH2PO4–(NH2)2CO–H2O and Its Ternary Subsystem KH2PO4–(NH2)2CO–H2O at 303.15 K
The phase equilibria of the quaternary system KCl–KH2PO4–(NH2)2CO–H2O and its ternary subsystem KH2PO4–(NH2)2CO–H2O at 303.15 K were studied by the isothermal dissolution equilibrium method, and the phase diagrams were plotted. The equilibrium solid phase was identified by Schreinemaker’s wet residue method and X-ray diffraction (XRD). The ternary subsystem is a simple cosaturated system, the phase diagram contains one saturation point, two univariate curves, and three crystallization regions. A comparison of the phase diagrams of ternary subsystem at different temperatures shows that the cocrystallization region of KH2PO4 and (NH2)2CO decreases with the increase of temperature. The phase diagram of the quaternary system shows that the system is a simple cosaturated system, including one invariant point, three univariant curves, and three crystallization regions. Based on the Pitzer–H–W model, the lacking particle interaction parameters were regressed using the solubility data of the ternary systems and used to calculate the solubility data. By comparing the experimental value with the calculated value, the results both indicated that the experiment and theoretical calculation have good consistency, and the Pitzer–H–W model is suitable for the electrolyte and neutral molecule solution systems.
期刊介绍:
The Journal of Chemical & Engineering Data is a monthly journal devoted to the publication of data obtained from both experiment and computation, which are viewed as complementary. It is the only American Chemical Society journal primarily concerned with articles containing data on the phase behavior and the physical, thermodynamic, and transport properties of well-defined materials, including complex mixtures of known compositions. While environmental and biological samples are of interest, their compositions must be known and reproducible. As a result, adsorption on natural product materials does not generally fit within the scope of Journal of Chemical & Engineering Data.