Caitlin L. Bentley, Mariam Y. Balogun, Oscar Morales-Collazo, Joan F. Brennecke
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引用次数: 0
摘要
与纯离子液体相比,离子液体(ILs)的混合物为改变物理和化学特性提供了引人入胜的可能性。在这里,我们研究了二氧化碳和 N2 在 313.2 K 温度下在 1-乙基-3-甲基咪唑鎓双(三氟甲基磺酰基)亚胺([emim][TFSI])与 1-乙基-3-甲基咪唑鎓四氟硼酸盐([emim][BF4])的混合物中的溶解度。二氧化碳的溶解度是在最高 15 巴的压力下测得的,而 N2 的溶解度是在最高 140 巴的压力下测得的。这两种气体都是通过物理溶解的方式溶解在这些惰性气体中的。对于这两种混合物,混合物中 CO2 和 N2 的亨利定律常数比纯 IL 中亨利定律常数的摩尔分数加权线性组合要低(即溶解度更高)。事实上,混合物中这两种气体的亨利定律常数与纯 IL 亨利定律常数的自然对数的摩尔分数加权线性组合完全吻合。不过,在任何情况下,两种气体在 IL 混合物中的溶解度都不会大于或小于在两种纯 IL 中的溶解度。因此,根据 IL 混合物中纯气体溶解度的测量结果,IL 混合物中预期的 CO2/N2 选择性总是介于纯 IL 的 CO2/N2 选择性值之间。
CO2/N2 Selectivity in [emim][BF4] + [emim][TFSI] and [emim][DCA] + [emim][TFSI] Ionic Liquid Mixtures
Mixtures of ionic liquids (ILs) present intriguing possibilities for modifying both physical and chemical properties relative to the pure ILs. Here we investigate the solubility of CO2 and N2 in mixtures of 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([emim][TFSI]) with 1-ethyl-3-methylimidazolium tetrafluoroborate ([emim][BF4]) at 313.2 K and 1-ethyl-3-methylimidazolium dicyanamide ([emim][DCA]) at 313.2 and 333.2 K. CO2 solubilities are measured at pressures up to 15 bar, while N2 solubilities were measured up to 140 bar. Both gases dissolve in these ILs by physical dissolution. For both mixtures the Henry’s Law constants for CO2 and N2 in the mixtures are lower (i.e., higher solubility) than a mole fraction weighted linear combination of the Henry’s Law constants in the pure ILs. In fact, the Henry’s Law constants for both gases in the mixtures are adequately fit with a mole fraction weighted linear combination of the natural logarithm of the pure IL Henry’s Law constants. However, in no case is the solubility of either gas in the IL mixtures greater than or less than the solubilities in the two pure ILs. As a result, the anticipated CO2/N2 selectivity in the IL mixtures, based on pure gas solubility measurements in the IL mixtures, is always between the values of the CO2/N2 selectivity for the pure ILs.
期刊介绍:
The Journal of Chemical & Engineering Data is a monthly journal devoted to the publication of data obtained from both experiment and computation, which are viewed as complementary. It is the only American Chemical Society journal primarily concerned with articles containing data on the phase behavior and the physical, thermodynamic, and transport properties of well-defined materials, including complex mixtures of known compositions. While environmental and biological samples are of interest, their compositions must be known and reproducible. As a result, adsorption on natural product materials does not generally fit within the scope of Journal of Chemical & Engineering Data.