向列液晶弹性体的动态大应变配方

IF 1.9 4区 工程技术 Q3 MECHANICS Continuum Mechanics and Thermodynamics Pub Date : 2024-05-18 DOI:10.1007/s00161-024-01307-2
Francesca Concas, Michael Groß
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引用次数: 0

摘要

液晶弹性体(LCEs)是一类在向列状态下表现出各向异性的材料,其主要原因在于被称为中间体的杆状分子的主要取向。介原的重新取向导致 LCE 具有众所周知的致动特性,即在特定外部刺激(如温度升高)的作用下产生异常大的变形。向列 LCE 的另一个主要特征是,在与介质取向垂直的方向上拉伸时,能够在恒定应力的作用下发生变形。在此高原阶段,介质会朝着拉伸方向旋转。这种特性被定义为向列 LCE 的半软弹性响应。我们的目标是根据基于变异的混合有限元公式,用动态有限元方法对半软行为进行建模。刚性介质相对于连续旋转的重新定向过程由微钻孔自由度引入。适当的自由能函数是实现上述特征的关键。从基于小应变理论的等温自由能函数开始,我们旨在通过确定张量不变式将其扩展到大应变框架中。在这项工作中,我们分析了张量不变式对有限元公式机械响应的等温影响,并证明其时空离散化在离散设置中保留了机械平衡定律。
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Dynamic large strain formulation for nematic liquid crystal elastomers

Liquid crystal elastomers (LCEs) are a class of materials which exhibit an anisotropic behavior in their nematic state due to the main orientation of their rod-like molecules called mesogens. The reorientation of mesogens leads to the well-known actuation properties of LCEs, i.e. exceptionally large deformations as a consequence of particular external stimuli, such as temperature increase. Another key feature of nematic LCEs is the capability to undergo deformation by constant stresses while being stretched in a direction perpendicular to the orientation of mesogens. During this plateau stage, the mesogens rotate towards the stretching direction. Such characteristic is defined as semisoft elastic response of nematic LCEs. We aim at modeling the semisoft behavior in a dynamic finite element method based on a variational-based mixed finite element formulation. The reorientation process of the rigid mesogens relative to the continuum rotation is introduced by micropolar drilling degrees of freedom. Responsible for the above-mentioned characteristics is an appropriate free energy function. Starting from an isothermal free energy function based on the small strain theory, we aim to widen it into the framework of large strains by identifying tensor invariants. In this work, we analyze the isothermal influence of the tensor invariants on the mechanical response of the finite element formulation and show that its space-time discretization preserves mechanical balance laws in the discrete setting.

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来源期刊
CiteScore
5.30
自引率
15.40%
发文量
92
审稿时长
>12 weeks
期刊介绍: This interdisciplinary journal provides a forum for presenting new ideas in continuum and quasi-continuum modeling of systems with a large number of degrees of freedom and sufficient complexity to require thermodynamic closure. Major emphasis is placed on papers attempting to bridge the gap between discrete and continuum approaches as well as micro- and macro-scales, by means of homogenization, statistical averaging and other mathematical tools aimed at the judicial elimination of small time and length scales. The journal is particularly interested in contributions focusing on a simultaneous description of complex systems at several disparate scales. Papers presenting and explaining new experimental findings are highly encouraged. The journal welcomes numerical studies aimed at understanding the physical nature of the phenomena. Potential subjects range from boiling and turbulence to plasticity and earthquakes. Studies of fluids and solids with nonlinear and non-local interactions, multiple fields and multi-scale responses, nontrivial dissipative properties and complex dynamics are expected to have a strong presence in the pages of the journal. An incomplete list of featured topics includes: active solids and liquids, nano-scale effects and molecular structure of materials, singularities in fluid and solid mechanics, polymers, elastomers and liquid crystals, rheology, cavitation and fracture, hysteresis and friction, mechanics of solid and liquid phase transformations, composite, porous and granular media, scaling in statics and dynamics, large scale processes and geomechanics, stochastic aspects of mechanics. The journal would also like to attract papers addressing the very foundations of thermodynamics and kinetics of continuum processes. Of special interest are contributions to the emerging areas of biophysics and biomechanics of cells, bones and tissues leading to new continuum and thermodynamical models.
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