{"title":"利用氢转移氧化还原体系进行钯铁双金属催化的醇和硝基烯烃交叉偶联反应","authors":"Rikiya Horikawa, Shoma Ishii, Urara Shinozaki, Reika Midorikawa, Takamichi Mori, Masanari Kimura","doi":"10.1093/chemle/upae094","DOIUrl":null,"url":null,"abstract":"\n A Pd/Fe bimetallic catalyst in the presence of the Xantphos ligand promoted the cross-coupling reaction of alcohols and nitroarenes via a hydrogen-transfer redox system. The consecutive formation of aldimines from benzyl alcohols and nitroarenes proceeded in three steps in a single manipulation: oxidation of alcohols, reduction of nitroarenes, and dehydrative condensation of aldehydes and aminoarenes.","PeriodicalId":9862,"journal":{"name":"Chemistry Letters","volume":null,"pages":null},"PeriodicalIF":1.4000,"publicationDate":"2024-05-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Palladium-Iron Bimetallic-Catalyzed Cross-Coupling Reaction of Alcohols and Nitroarenes Using a Hydrogen-Transfer Redox System\",\"authors\":\"Rikiya Horikawa, Shoma Ishii, Urara Shinozaki, Reika Midorikawa, Takamichi Mori, Masanari Kimura\",\"doi\":\"10.1093/chemle/upae094\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"\\n A Pd/Fe bimetallic catalyst in the presence of the Xantphos ligand promoted the cross-coupling reaction of alcohols and nitroarenes via a hydrogen-transfer redox system. The consecutive formation of aldimines from benzyl alcohols and nitroarenes proceeded in three steps in a single manipulation: oxidation of alcohols, reduction of nitroarenes, and dehydrative condensation of aldehydes and aminoarenes.\",\"PeriodicalId\":9862,\"journal\":{\"name\":\"Chemistry Letters\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.4000,\"publicationDate\":\"2024-05-17\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemistry Letters\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1093/chemle/upae094\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemistry Letters","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1093/chemle/upae094","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Palladium-Iron Bimetallic-Catalyzed Cross-Coupling Reaction of Alcohols and Nitroarenes Using a Hydrogen-Transfer Redox System
A Pd/Fe bimetallic catalyst in the presence of the Xantphos ligand promoted the cross-coupling reaction of alcohols and nitroarenes via a hydrogen-transfer redox system. The consecutive formation of aldimines from benzyl alcohols and nitroarenes proceeded in three steps in a single manipulation: oxidation of alcohols, reduction of nitroarenes, and dehydrative condensation of aldehydes and aminoarenes.
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