动态运行条件下 PEM 水电解槽堆性能的实验研究

Jingjing Liu, Liuyi Huang, J. Leveneur, Holger Fiedler, Samuel Jack Clarke, Thea Larsen, J. Kennedy, Mark Taylor
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摘要

水电解已被用于生产绿色氢气,而确定最佳运行参数对于提高其能效和能耗至关重要。本文使用一个商用质子交换膜(PEM)水电解槽(180 W)来证明工作电流变化、温度和水流量之间的相关性及其对电解槽热性能和电性能的影响。研究发现,在长期运行的电解槽中,电流控制制度和温度控制可以抵消电压老化,对 H2 的生产率没有负面影响。对于受控的递减电流路径,在中等工作电流范围内,电解槽的能效提高了 5%,与标准操作(57.8 kWh-kg-1H2)相比,可节省 3.7% 的特定能耗。这些结果为优化运行条件以进一步提高电池能效和降低能耗提供了启示。这一新发现为开发一种通过水电解进行长期绿色制氢的节能和成本节约型操作方法提供了启示。
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Experimental Investigation of PEM Water Electrolyser Stack Performance Under Dynamic Operation Conditions
Water electrolysis has been used to produce green hydrogen, for which identifying optimum operation parameters is crucial to improve its energy efficiency and energy consumption. This paper used a commercial proton exchange membrane (PEM) water electrolyser stack (180 W) to demonstrate the correlation between operating current change, temperature, and water flow rate and their impact on the thermal and electrical performance of the stack. It was found that the current control regime and temperature control can offset the voltage ageing in a long-term operating electrolyser with no negative impact on the H2 production rate. For a controlled decreasing current path, in the medium range of operating current, the stack’s energy efficiency was improved by 5%, and 3.7% specific energy consumption can be saved comparing to the standard operation (57.8 kWh·kg-1H2). The results provide insights into the potential optimisation in operation conditions to further increase cell energy efficiency and reduce energy consumption. This new finding sheds light on developing an energy- and cost-saving operating method for long-term green hydrogen production via water electrolysis.
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