基于 PET-PAN 和 LDH-hybrid 改性的复合电纺丝膜,有望成为去除废水中污染物的吸附剂

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引用次数: 0

摘要

目前的研究揭示了一种新型纳米纤维复合膜的制作方法,该膜由 PET-PAN 与 Mg-Al-LDH-PVA 通过电纺丝工艺改性而成。纳米复合膜的表征采用了不同的技术,即 SEM、EDS、FTIR、XRD 和水接触角,以评估其结构和表面形态。优化后的纳米膜被用作去除废水中有毒阴离子染料 Eriochrome Black T (EBT) 和阳离子染料甲基蓝 (MB) 的有效吸附剂。实验结果表明,PPLP3 膜在 pH 值分别为 3 和 7 的水溶液中具有去除 EBT(83%)和 MB(52%)的潜力。经计算,PPLP3 纳米复合膜的最佳吸附容量为 7.3 mg.g-1,其伪二阶动力学和朗缪尔吸附等温线的拟合效果良好,R2 值分别为 0.964 和 0.997。合成的纳米复合膜可用于有效吸附不同废水中的污染物。
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Composite electrospun membranes based on PET-PAN modified with LDH-hybrid as promising adsorbent for pollutants removal from wastewater
The current work reveals the fabrication of a novel nanofiber composite membrane of PET-PAN modified with Mg-Al-LDH-PVA through electrospinning process. The nanocomposite membranes characterization was conducted with different techniques i.e. SEM, EDS, FTIR, XRD, and water contact angle to evaluate the structure and surface morphology. The optimized nanomembrane was utilized as a useful adsorbent for removal of toxic anionic dye Eriochrome Black T (EBT) and cationic dye Methylene blue (MB) from wastewater. Experimental results identified that PPLP3 membrane has a potential for the removal of EBT (83%) and MB (52%) at pH 3 and 7, respectively, from aqueous solution. The optimum adsorption capacity of PPLP3 nanocomposite membrane was identified and calculated as 7.3 mg.g-1 followed by the pseudo 2nd order kinetics and Langmuir adsorption isotherm fit well with R2 values of 0.964 and 0.997, respectively. The synthesized nanocomposite membrane could be utilized for effective adsorption of contaminations from different wastewaters.
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