使用栗壳衍生活性炭作为吸附剂对水进行脱氟处理的研究

Firdous Ahmad Dar, Swamy Kurella
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引用次数: 0

摘要

本研究旨在利用栗壳生产新型经济有效的碱处理吸附剂,以去除水中的氟化物,并探索在不同功能参数下热解温度对氟化物净化的影响。利用 BET、傅立叶变换红外光谱、X 射线衍射和扫描电镜对所得活性炭的微观结构和形态特征进行了深入研究。对所制备的吸附材料处理和修复含氟水的效果进行了评估。研究了几个因素的影响,包括吸附剂的剂量、氟的初始污染、pH 值以及效果。数据显示,在处理时间为 5 小时、吸附剂用量为 0.5 克/升、pH 值为 6 时,吸附率最高。观察结果与 Freundlich 等温线模型和假二阶动力学模型拟合良好。在 800 °C 下制备的吸附剂在 pH 值为 6 的 10 mg/L 氟化物溶液中吸附氟化物的能力和效率最高,达到 78%。对吸附和再生进行的其他研究表明,在重复进行四次涉及再生的操作后,吸附潜能降低到 10%,从而展示了该吸附剂可重复使用的多功能适用性。
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Study on Defluoridation of Water by Using Activated Carbon Derived from Chestnut Shell as Adsorbent
The present work intended to produce new cost-effective alkali-treated adsorbents from chestnut shells with the purpose of removing fluoride from water, and to explore the effect of pyrolysis temperature on fluoride decontamination at different functional parameters. The microstructure and morphological characteristics of the resulting activated carbons were thoroughly investigated using BET, FTIR, XRD and SEM. The effectiveness of the prepared adsorbent materials in treating and remediating fluorinated water was evaluated. The impacts of several factors, including the dose of the adsorbent, the initial contamination of fluoride, pH as well as the effectiveness were investigated. In accordance with the data the highest adsorption was found to be at a 6 pH during 5 hours of processing duration and 0.5 g/L of dosage of adsorbent. The observational results were well-fit by the Freundlich isotherm model and the pseudo-second-order kinetic model. The highest ability and efficiency to adsorb fluoride was observed as 78%, at a pH value of 6 for 10 mg/L fluoride solution by the adsorbent prepared at 800 °C. Additional research on adsorption along with rejuvenation revealed that the reduction in adsorption potential to 10% following four repetitions of operation involving regeneration, thereby showcasing the adsorbent's versatile applicability for repeated use.
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