{"title":"癸钨酸盐与铬催化相结合实现 1,3-丁二烯的氧化还原中性 1,2-二碳化反应","authors":"D. Ding, Pu-Sheng Wang","doi":"10.1055/a-2328-3037","DOIUrl":null,"url":null,"abstract":"Homoallylic alcohol is a significantly useful intermediate in organic synthesis. Here we establish a three-component NHK-type reaction of 1,3-butadiene, aldehydes and aliphatic C–H partners by merging decatungstate and chromium catalysis, enabling a modular, redox-neutral and atom-economic strategy to access a diverse range of homoallylic alcohols.","PeriodicalId":510101,"journal":{"name":"Synthesis","volume":"136 27","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-05-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Redox-Neutral 1,2-Dicarbonfunctionlization of 1,3-Butadiene by Merging Decatungstate and Chromium Catalysis\",\"authors\":\"D. Ding, Pu-Sheng Wang\",\"doi\":\"10.1055/a-2328-3037\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Homoallylic alcohol is a significantly useful intermediate in organic synthesis. Here we establish a three-component NHK-type reaction of 1,3-butadiene, aldehydes and aliphatic C–H partners by merging decatungstate and chromium catalysis, enabling a modular, redox-neutral and atom-economic strategy to access a diverse range of homoallylic alcohols.\",\"PeriodicalId\":510101,\"journal\":{\"name\":\"Synthesis\",\"volume\":\"136 27\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-05-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Synthesis\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1055/a-2328-3037\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Synthesis","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1055/a-2328-3037","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
摘要
均烯丙基醇是有机合成中一种非常有用的中间体。在这里，我们通过蜕钨酸盐和铬催化，建立了一个由 1,3-丁二烯、醛和脂肪族 C-H 合伙人组成的三组分 NHK 型反应，从而实现了一种模块化、氧化还原中性和原子经济的策略，以获得各种均烯丙基醇。
Redox-Neutral 1,2-Dicarbonfunctionlization of 1,3-Butadiene by Merging Decatungstate and Chromium Catalysis
Homoallylic alcohol is a significantly useful intermediate in organic synthesis. Here we establish a three-component NHK-type reaction of 1,3-butadiene, aldehydes and aliphatic C–H partners by merging decatungstate and chromium catalysis, enabling a modular, redox-neutral and atom-economic strategy to access a diverse range of homoallylic alcohols.
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