具有优异电化学性能的棒状 MnMoO4 用作检测三乙胺的传感材料

Shuai-Shuai Lv, Yu-Feng Liu, Si-Qi Jiao, Chuning Jiang, Cheng Zhang, Xiaohong Zheng
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摘要

MnMoO4 具有优异的电化学性能,被广泛应用于电化学领域。本研究采用简单的溶热法成功制备了具有棒状结构的 MnMoO4,并将其用作气体传感器的敏感材料。气体传感性能表明,基于 MnMoO4 的传感器对 50 ppm 三乙胺的响应为 224.2,是纯 MoO3 的 2.3 倍。MnMoO4 具有更高灵敏度的原因是氧空位含量的增加使 MnMoO4 材料表面具有丰富的活性位点。此外,其较大的基线电阻也有利于提高气体灵敏度。这些因素使得基于 MnMoO4 的传感器对三乙胺表现出较高的响应。此外,该传感器还具有优异的选择性、令人满意的重复性以及在化学敏化和协同作用下对三乙胺的长期稳定性。这项工作为 MnMoO4 在气体传感器中的应用提供了一种新思路。
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Rod-Like MnMoO4 with Excellent Electrochemical Performance as Sensing Material to Detect Triethylamine
MnMoO4 has excellent electrochemical properties and is widely used in the field of electrochemistry. In this study, MnMoO4 with rod-like structure was successfully prepared by simple solvothermal method and used as sensitive material for gas sensors. The gas sensing performance shows that the response of MnMoO4-based sensor to 50 ppm triethylamine is 224.2, which is 2.3 times higher than that of pure MoO3. That reason why MnMoO4 exhibits better sensitivity is that the increase of oxygen vacancy content gives the surface of MnMoO4 material abundant active sites. In addition, its large baseline resistance is also conducive to the improvement of gas sensitivity. These factors make the MnMoO4-based sensor exhibit high response to triethylamine. What’s more, the sensor also has excellent selectivity, satisfactory repeatability, and long-term stability to triethylamine under chemical sensitization and synergistic action. This work provides a new thinking for the application of MnMoO4 in gas sensors.
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