利用穿心莲叶提取物对掺杂锡的 CuO 纳米复合材料进行表征和抗菌研究

IF 17.7 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-05-13 DOI:10.15251/djnb.2024.192.619
S. Subha, M. Nagarajan, S. Saseetha, S. C. Vella Durai
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引用次数: 0

摘要

为了合成 CuO、SnO2 和掺杂 Sn 的 CuO 纳米复合材料,本研究采用了可获得的无毒材料,特别是从 Centratherum punctatum 中提取的叶提取物,以应用绿色化学的概念和实践。这些方法既经济又环保。此外,还采用了一系列全面的表征技术,包括傅立叶变换红外光谱、X 射线衍射和紫外-可见光谱,以确认所有制得的纳米材料的结构。此外,还使用了 FESEM 和 EDAX 来分析最近生产的纳米材料的形态和元素组成。掺锡后,紫外可见光研究中观察到的红移表明光带隙值下降。傅立叶变换红外分析证实了样品中存在不同的官能团。对于 CuO NPs、SnO2 和掺锡 CuO NCs,X 射线衍射结果表明所制备颗粒的结晶尺寸分别为 6 nm、21 nm 和 29 nm。振动样品磁力计实验验证了所制样品在室温下的铁磁性、二磁性和超顺磁性特性。循环伏安法用于检测纳米粒子的电化学分析。使用掺杂锡的 CuO 纳米复合材料,在 10 mV/s 的电流密度下,显示出约 187 Fg-1 的高比电容值。电化学研究发现,所生产的纳米材料适用于电容行为。毕竟,每个孔周围都存在抑制区,这使我们得出结论,纳米粒子对金黄色葡萄球菌和大肠杆菌等致病菌株具有抗菌活性。
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Characterization and antibacterial studies of Sn doped CuO nanocomposite using centratherum punctatum leaf extract
In order to synthesize CuO, SnO2, and Sn doped CuO nanocomposites, accessible and non-toxic materials, specifically leaf extract from Centratherum punctatum, were used in this work to apply the concepts and practices of green chemistry. These methods are both economical and environmentally friendly. A comprehensive range of characterisation techniques, including as FTIR, X-ray diffraction, and UV-vis spectroscopy, were also used to confirm the structures of all the produced nanomaterials. Instead, FESEM and EDAX were used to analyze the morphologies and elemental composition of recently produced nanomaterials. A decline in the optical band gap values was indicated by the red shift observed in the UV-vis study following tin doping. A sample's presence of different functional groups is confirmed by FT-IR analysis. For CuO NPs, SnO2, and Sn doped CuO NCs, the XRD results yielded crystallite sizes of 6 nm, 21 nm, and 29 nm, respectively, for the produced particles. The ferromagnetic, diamagnetic, and super paramagnetic characteristics of the produced samples at room temperature were validated by vibrating sample magnetometer experiments. Cyclic voltammetry is used to examine the nanoparticles' electrochemical analysis. Using Sn doped CuO nanocomposite material, it shows a high specific capacitance value of about ~187 Fg-1 at a current density of 10 mV/s. It was found from the electrochemical studies that the produced nanomaterials are suitable for capacitive behaviour. After all, the presence of inhibition zones surrounding each well led us to the conclusion that the nanoparticles exhibited antibacterial activity against the pathogenic strains of Staphylococcus aureus and Escherichia coli.
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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