创新的发动机试验台装置,用于测试 CNG-SI 运行的废气后处理和详细气体种类分析

Sebastian Tomin, Kevin Keller, Uwe Wagner, Patrick Lott, Thomas Koch, Olaf Deutschmann
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摘要

要有效减少甲烷滑移,就必须准确了解实际条件下废气处理后的情况。由于不可能在实验室规模上生产近似系列几何形状的催化转换器,因此有必要使用小得多的催化剂样品。因此,我们设计了一个发动机试验台,借助空间速度和温度控制来确保此类样品的真实运行条件。空间速度的实际值和参考值之间的比较结果是,平均偏差很小,仅为 0.1%。此外,对催化剂的压力条件进行了测量,结果显示压力振荡从发动机出口处开始传播,结合空间速度的调节,表明催化剂样品可以应用真实的条件。随后,使用傅立叶变换红外光谱仪对废气浓度进行了监测。使用的催化剂材料是 Al2O3 上的 PdO,这是甲烷氧化的常用催化剂。测量结果表明,在贫化条件下,CH4 转化率较高,但低于完全转化率。在对纯粹的化学计量运行和抖动进行最后比较时,对测试期间的 CH4 转化率过程进行了更仔细的检查。除了在催化剂前后采样外,还利用特殊测量技术对催化剂通道内的废气成分进行了空间分辨率测量。在 CH4 排放的时间过程中,可以看到由于操作模式的改变而产生的稳定效果,这表明抖动似乎可以防止进一步的失活。
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Innovative engine test bench set-up for testing of exhaust gas aftertreatment and detailed gas species analysis for CNG-SI-operation

For an efficient reduction of methane slip, a precise understanding of exhaust gas after treatment under real conditions is essential. Since it is not possible to produce catalytic converters in near-series geometry on a laboratory scale, it is necessary to resort to significantly smaller sample catalysts. Therefore, an engine test bench was designed to ensure real operating conditions for such samples with the help of space velocity and temperature control. A comparison between the actual and reference values of the space velocity results in a small deviation of 0.1% on average. Furthermore, the pressure conditions at the catalyst have been measured showing a propagation of pressure oscillations from the engine outlet which in combination with the space velocity regulation show that real conditions could be applied to the catalyst sample. Subsequently, the exhaust gas concentrations were monitored with a Fourier transform infrared spectrometer. The catalyst material used is PdO on Al2O3, common for methane oxidation. The measurements show that the CH4 conversion is higher under lean conditions, but is below complete conversion. In a final comparison between purely stoichiometric operation and dithering, the course of the CH4 conversion rate over the test period is examined more closely. In addition to sampling pre- and post-catalyst, the exhaust gas composition is measured spatially resolved within a catalyst channel using special measurement technology. In the temporal course of the CH4 emissions, a stabilizing effect due to the change of the operating mode can be seen, showing that dithering seems to prevent further deactivation.

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