利用原子吸收光谱法比较特定加工罐装番茄酱和瓶装番茄酱中的重金属残留量

K. V. Veloo, H.I. Tan
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摘要

重金属被用于制造各种包装材料,如罐头和玻璃瓶容器。测定加工食品中的重金属浓度对于识别特定的可能有害的金属污染物和提高公众的食用意识至关重要。采用原子吸收光谱法(AAS)分析了在马来西亚销售的五种不同品牌的罐装番茄酱和瓶装番茄酱共十个样本中的铅(Pb)、镉(Cd)、铁(Fe)、锌(Zn)、铬(Cr)和镍(Ni)金属残留物的浓度。所有样本的重金属平均浓度按递增顺序排列:镉 > 镍 > 铬 > 铅 > 锌 > 铁。金属含量最高的是铁(69.93 毫克/千克),最低的是镉(0.01 毫克/千克)。除锌外,所有样本中的铅、铬和镍的浓度都超过了世界卫生组织(2011 年)、欧盟委员会(2006 年)和马来西亚食品法案和条例(1985 年)规定的允许限值。罐装番茄酱和瓶装番茄酱中的重金属浓度存在明显差异(p˂0.05)。因此,这项研究建议对农业环境质量和工业加工程序进行有效监测和检查。
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Comparison of heavy metal residue in selected processed canned tomato paste and bottled tomato sauce using atomic absorption spectrometry
Heavy metals are used to manufacture various types of packaging materials such as cans and glass bottle containers. Determination of heavy metal concentration presence in processed food products is crucial to identify specific possibly hazard metal contaminants and create public awareness upon consumption. A total of ten samples consisting of five different brands of canned tomato paste and bottled tomato sauce sold in Malaysia were analysed for the concentration of lead (Pb), cadmium (Cd), iron (Fe), zinc (Zn), chromium (Cr) and nickel (Ni) metals residues by Atomic Absorption Spectrometry (AAS). The average heavy metals concentration of all samples was arranged in increasing order, Cd > Ni > Cr > Pb > Zn > Fe. The highest level of metal was Fe (69.93 mg/kg) while the lowest was Cd (0.01 mg/kg). The concentration of Pb, Cr and Ni in all samples exceed the permissible limit set by the World Health Organisation 2011, the European Commission 2006 and the Malaysia Food Act and Regulation 1985 except Zn. There is a significant difference between heavy metal concentrations in canned tomato paste and bottled tomato sauce (p˂0.05). Therefore, this study suggests efficient monitoring and inspection of both agricultural environment quality and industrial processing procedures.
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