质子交换膜燃料电池用纳米碳基电催化/电极材料的最新进展:综述

Catalysts Pub Date : 2024-05-03 DOI:10.3390/catal14050303
A. A. Zasypkina, Nataliya A. Ivanova, D. D. Spasov, R. Mensharapov, M. Sinyakov, Sergey A. Grigoriev
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引用次数: 0

摘要

质子交换膜燃料电池市场发展的全球性问题是通过提高阴极氧还原反应的效率和延长电化学装置的使用寿命来降低装置成本。燃料电池性能的损失是由于催化层在高电势、温度和湿度条件下发生的各种降解机制造成的。本综述主要介绍通过在电催化剂和其他电极材料的成分中引入结构碳成分来提高其效率和耐用性方面的最新进展。文章介绍了主要的合成方法、材料的物理化学和电化学特性,以及在此基础上的设备性能。揭示了结构碳电极材料的组成与性能之间的主要相关性,这些相关性可为突出问题提供成功的解决方案。
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Recent Advances in the Development of Nanocarbon-Based Electrocatalytic/Electrode Materials for Proton Exchange Membrane Fuel Cells: A Review
The global issue for proton exchange membrane fuel cell market development is a reduction in the device cost through an increase in efficiency of the oxygen reduction reaction occurring at the cathode and an extension of the service life of the electrochemical device. Losses in the fuel cell performance are due to various degradation mechanisms in the catalytic layers taking place under conditions of high electric potential, temperature, and humidity. This review is devoted to recent advances in the field of increasing the efficiency and durability of electrocatalysts and other electrode materials by introducing structured carbon components into their composition. The main synthesis methods, physicochemical and electrochemical properties of materials, and performance of devices on their basis are presented. The main correlations between the composition and properties of structured carbon electrode materials, which can provide successful solutions to the highlighted issues, are revealed.
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