在宽热源温度范围内实现高效率的集成式空气桥串联热光电技术

IF 19.3 1区 材料科学 Q1 CHEMISTRY, PHYSICAL ACS Energy Letters Pub Date : 2024-05-20 DOI:10.1021/acsenergylett.4c00774
Bosun Roy-Layinde, Jihun Lim, Andrej Lenert* and Stephen R. Forrest*, 
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引用次数: 0

摘要

机械堆叠的串联热光电(TPV)电池具有集成的 InGaAs 和 InGaAsP 子电池空气桥,可实现较高的光谱效率和发射温度通用性。与缺乏空气桥的电池相比,对置单空气桥电池上电极的热压焊接提高了带外反射率(ROUT)。我们报告了一种 0.74/0.74 eV 的同质串联电池,其 ROUT = 96.4%。当以多终端排列方式运行时,同型串联电池的效率达到 38%,与同类双终端配置相比,绝对效率提高了 20%。我们还展示了 0.9/0.74 eV 的异质串联,其 ROUT = 97.2%,光谱效率接近 80%。通过最大限度地减少与寄生吸收和电流失配相关的损耗,该串联器件在保持高效率的同时,大幅扩展了发射温度范围。这使得储能成本降低了 40% 以上。空气桥串联技术为高性能串联电池铺平了道路,使其能够不受子电池材料选择的限制,与各种热源兼容。
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Integrated Air-Bridge Tandem Thermophotovoltaics with High Efficiency over a Broad Heat Source Temperature Range

Mechanically stacked, tandem thermophotovoltaic (TPV) cells featuring integrated air-bridge InGaAs and InGaAsP subcells achieve high spectral efficiency and emission temperature versatility. Thermocompression bonding of electrodes on opposing single air-bridge cells increases out-of-band reflectance (ROUT) compared to cells lacking air bridges. We report a 0.74/0.74 eV homotandem exhibiting ROUT = 96.4%. When operated in a multiterminal arrangement, the homotandem achieves 38% efficiency, marking a 20% absolute improvement over a comparable two-terminal configuration. We also demonstrate a 0.9/0.74 eV heterotandem with ROUT = 97.2% and spectral efficiency approaching 80%. By minimizing losses associated with parasitic absorption and current mismatch, the tandem substantially expands the emission temperature range while preserving high efficiency. This leads to a reduction in the cost of energy storage by over 40%. The air-bridge tandem technology paves the way for high-performance tandem cells compatible with a variety of heat sources unrestricted by the choice of subcell materials.

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来源期刊
ACS Energy Letters
ACS Energy Letters Energy-Renewable Energy, Sustainability and the Environment
CiteScore
31.20
自引率
5.00%
发文量
469
审稿时长
1 months
期刊介绍: ACS Energy Letters is a monthly journal that publishes papers reporting new scientific advances in energy research. The journal focuses on topics that are of interest to scientists working in the fundamental and applied sciences. Rapid publication is a central criterion for acceptance, and the journal is known for its quick publication times, with an average of 4-6 weeks from submission to web publication in As Soon As Publishable format. ACS Energy Letters is ranked as the number one journal in the Web of Science Electrochemistry category. It also ranks within the top 10 journals for Physical Chemistry, Energy & Fuels, and Nanoscience & Nanotechnology. The journal offers several types of articles, including Letters, Energy Express, Perspectives, Reviews, Editorials, Viewpoints and Energy Focus. Additionally, authors have the option to submit videos that summarize or support the information presented in a Perspective or Review article, which can be highlighted on the journal's website. ACS Energy Letters is abstracted and indexed in Chemical Abstracts Service/SciFinder, EBSCO-summon, PubMed, Web of Science, Scopus and Portico.
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