发掘癸二酸盐的潜力:研究癸二酸盐在抑制有机涂层钢丝状腐蚀中的作用

Metals Pub Date : 2024-05-24 DOI:10.3390/met14060623
Andrea Cristoforetti, Stefano Rossi, F. Deflorian, M. Fedel
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摘要

这项研究调查了癸二酸盐作为丙烯酸涂层钢的缓蚀剂的效果。具体来说,研究通过一项选定的老化试验,考察了癸二酸盐对缓解一种常见的涂料脱层现象(即丝状腐蚀(FFC))的影响,该试验旨在强调所生产样品的降解。研究证明,癸二酸盐是一种有效的有机分子,可增强钢材的耐腐蚀性。通过基于电化学阻抗光谱测量和电位极化曲线的电化学表征,包括基于在 FFC 模拟电解质中获得的测量结果应用 FFC 易感性预测方法,对这种功效进行了评估。与缺乏抑制剂的条件相比,在接近中性的生理盐水溶液中测得的抑制效率为 98%。在全氟碳化物模拟过程中,观察到的主要影响与阴极活性演变的减少有关。此外,还发现腐蚀蠕变演化明显减少了 35%。这些实验结果与模拟研究预测的结果非常吻合。
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Unlocking the Potential of Sebacate: Investigating Its Role in the Inhibition of Filiform Corrosion on Organic Coated Steel
The study investigated the effect of sebacate as a corrosion inhibitor for acrylic-coated steel. Specifically, it examined its impact on mitigating a frequent case of paint delamination, known as filiform corrosion (FFC), through a chosen weathering test designed to stress the degradation of the produced samples. Sebacate was demonstrated to be an efficient organic molecule for enhancing the corrosion resistance of steel. This efficacy was evaluated through electrochemical characterization based on electrochemical impedance spectroscopy measurements and potentiodynamic polarization curves, including the application of an FFC susceptibility prediction methodology based on measurements obtained in FFC-simulated electrolytes. An inhibition efficiency of 98% was measured in near-neutral saline solutions compared to conditions lacking inhibitor presence. During FFC simulation, the primary effect observed was associated with a reduction in cathodic activity evolution. Furthermore, a significant reduction in corrosion creep evolution of 35% was found. These experimental findings aligned closely with the outcomes projected by the simulated investigations.
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