Olha Masiuchok, Łukasz Otulakowski, Karolina Olszowska, Paweł Chaber, Aleksander Foryś, Yevheniia Buinova, Roman Kolisnyk, Hanna Myalska-Głowacka, Piotr Szperlich, Bartłomiej Toroń, Urszula Szeluga, Marcin Godzierz
{"title":"用于机械能收集的聚苯乙烯/BiFeO3 0-3 薄膜纳米复合材料的工程设计","authors":"Olha Masiuchok, Łukasz Otulakowski, Karolina Olszowska, Paweł Chaber, Aleksander Foryś, Yevheniia Buinova, Roman Kolisnyk, Hanna Myalska-Głowacka, Piotr Szperlich, Bartłomiej Toroń, Urszula Szeluga, Marcin Godzierz","doi":"10.1002/admt.202302040","DOIUrl":null,"url":null,"abstract":"<p>This work describes impact of concentration of BiFeO<sub>3</sub> submicrometric particles on piezoelectric performance and structural characteristics of 0–3 polymer composites with a polystyrene matrix. Bismuth ferrite particles are fabricated using reverse co-precipitation method, followed by ultrasonic dispersion in a solvent to break up agglomerates formed during sintering, resulting in particles with a size of ≈200 nm. It is found that concentrations higher than 10 wt% BiFeO<sub>3</sub> lead to a disturbance in natural organization of polystyrene. The hindered organization of side-groups by submicrometric filler, occurring during solvent evaporation, strongly affects the mechanical properties of the finalcomposite, significantly increasing Young's modulus and tensile strength, but decreasing elongation. Such behavior is detected and described for the firsttime in literature. Piezoelectric examinations show that the thermal depolarization of nanogenerators has a different impact depending on the amountof piezoelectric phase. The study reveals that a voltage of over 4.8 V is generated when dynamic air pressure is applied at 11.54 bar for the composite containing only 2.5 wt% BiFeO<sub>3</sub>. For composites with 10% weight fraction or lower, decrease in generated voltage after thermal depolarization is about 24%, while for higher weight fractions (15 and 20 wt%) the decrease is around 35%.</p>","PeriodicalId":7292,"journal":{"name":"Advanced Materials Technologies","volume":null,"pages":null},"PeriodicalIF":6.4000,"publicationDate":"2024-05-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Engineering of Polystyrene/BiFeO3 0–3 Thin Film Nanocomposites for Mechanical Energy Harvesting\",\"authors\":\"Olha Masiuchok, Łukasz Otulakowski, Karolina Olszowska, Paweł Chaber, Aleksander Foryś, Yevheniia Buinova, Roman Kolisnyk, Hanna Myalska-Głowacka, Piotr Szperlich, Bartłomiej Toroń, Urszula Szeluga, Marcin Godzierz\",\"doi\":\"10.1002/admt.202302040\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>This work describes impact of concentration of BiFeO<sub>3</sub> submicrometric particles on piezoelectric performance and structural characteristics of 0–3 polymer composites with a polystyrene matrix. Bismuth ferrite particles are fabricated using reverse co-precipitation method, followed by ultrasonic dispersion in a solvent to break up agglomerates formed during sintering, resulting in particles with a size of ≈200 nm. It is found that concentrations higher than 10 wt% BiFeO<sub>3</sub> lead to a disturbance in natural organization of polystyrene. The hindered organization of side-groups by submicrometric filler, occurring during solvent evaporation, strongly affects the mechanical properties of the finalcomposite, significantly increasing Young's modulus and tensile strength, but decreasing elongation. Such behavior is detected and described for the firsttime in literature. Piezoelectric examinations show that the thermal depolarization of nanogenerators has a different impact depending on the amountof piezoelectric phase. The study reveals that a voltage of over 4.8 V is generated when dynamic air pressure is applied at 11.54 bar for the composite containing only 2.5 wt% BiFeO<sub>3</sub>. For composites with 10% weight fraction or lower, decrease in generated voltage after thermal depolarization is about 24%, while for higher weight fractions (15 and 20 wt%) the decrease is around 35%.</p>\",\"PeriodicalId\":7292,\"journal\":{\"name\":\"Advanced Materials Technologies\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":6.4000,\"publicationDate\":\"2024-05-23\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Advanced Materials Technologies\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/admt.202302040\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advanced Materials Technologies","FirstCategoryId":"88","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/admt.202302040","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Engineering of Polystyrene/BiFeO3 0–3 Thin Film Nanocomposites for Mechanical Energy Harvesting
This work describes impact of concentration of BiFeO3 submicrometric particles on piezoelectric performance and structural characteristics of 0–3 polymer composites with a polystyrene matrix. Bismuth ferrite particles are fabricated using reverse co-precipitation method, followed by ultrasonic dispersion in a solvent to break up agglomerates formed during sintering, resulting in particles with a size of ≈200 nm. It is found that concentrations higher than 10 wt% BiFeO3 lead to a disturbance in natural organization of polystyrene. The hindered organization of side-groups by submicrometric filler, occurring during solvent evaporation, strongly affects the mechanical properties of the finalcomposite, significantly increasing Young's modulus and tensile strength, but decreasing elongation. Such behavior is detected and described for the firsttime in literature. Piezoelectric examinations show that the thermal depolarization of nanogenerators has a different impact depending on the amountof piezoelectric phase. The study reveals that a voltage of over 4.8 V is generated when dynamic air pressure is applied at 11.54 bar for the composite containing only 2.5 wt% BiFeO3. For composites with 10% weight fraction or lower, decrease in generated voltage after thermal depolarization is about 24%, while for higher weight fractions (15 and 20 wt%) the decrease is around 35%.
期刊介绍:
Advanced Materials Technologies Advanced Materials Technologies is the new home for all technology-related materials applications research, with particular focus on advanced device design, fabrication and integration, as well as new technologies based on novel materials. It bridges the gap between fundamental laboratory research and industry.