Dzaky Dian Ruhimat, F. Failamani, Bambang Prijamboedi
{"title":"Ca2+ 取代的 Na2TiSiO5 自激活光致发光材料的结构和光致发光特性","authors":"Dzaky Dian Ruhimat, F. Failamani, Bambang Prijamboedi","doi":"10.5614/j.math.fund.sci.2023.55.2.6","DOIUrl":null,"url":null,"abstract":"The effects of Ca2+ substitution on the structural and optical properties of Na2TiSiO5 were studied. It was expected that the Ca2+ ions would replace Na+ ions and change the coordination of Ti4+-O2- as a luminescence center. Na2(1‑x)CaxTiSiO5 (x = 0.00, 0.50, 1.00) samples were synthesized using the solid-state method, and their structural properties, the local Ti4+-O2- coordination, the absorption spectra, and the photoluminescence properties were studied. The electronic structure of Na2(1-x)CaxTiSiO5 with x = 0.00 and 1.00 was also calculated using the Full Potential Linear Augmented Plane Wave (FP-LAPW) method to explain some of the observed properties. The Ca2+ substitution resulted in a phase transformation from an orthorhombic to a monoclinic structure. The number of TiO6 octahedra increased with the increase of Ca2+ and correlated with the decrease of PL emission intensity of the Na2(1‑x)CaxTiSiO5 samples. The Ti-3d bands in the CaTiSiO5 were more dispersive than in the Na2TiSiO5 and were responsible for the PL emission intensity reduction.","PeriodicalId":16255,"journal":{"name":"Journal of Mathematical and Fundamental Sciences","volume":null,"pages":null},"PeriodicalIF":0.5000,"publicationDate":"2024-05-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Structural and Photoluminescence Properties of Ca2+-Substituted Self-Activated Photoluminescence Material of Na2TiSiO5\",\"authors\":\"Dzaky Dian Ruhimat, F. Failamani, Bambang Prijamboedi\",\"doi\":\"10.5614/j.math.fund.sci.2023.55.2.6\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The effects of Ca2+ substitution on the structural and optical properties of Na2TiSiO5 were studied. It was expected that the Ca2+ ions would replace Na+ ions and change the coordination of Ti4+-O2- as a luminescence center. Na2(1‑x)CaxTiSiO5 (x = 0.00, 0.50, 1.00) samples were synthesized using the solid-state method, and their structural properties, the local Ti4+-O2- coordination, the absorption spectra, and the photoluminescence properties were studied. The electronic structure of Na2(1-x)CaxTiSiO5 with x = 0.00 and 1.00 was also calculated using the Full Potential Linear Augmented Plane Wave (FP-LAPW) method to explain some of the observed properties. The Ca2+ substitution resulted in a phase transformation from an orthorhombic to a monoclinic structure. The number of TiO6 octahedra increased with the increase of Ca2+ and correlated with the decrease of PL emission intensity of the Na2(1‑x)CaxTiSiO5 samples. The Ti-3d bands in the CaTiSiO5 were more dispersive than in the Na2TiSiO5 and were responsible for the PL emission intensity reduction.\",\"PeriodicalId\":16255,\"journal\":{\"name\":\"Journal of Mathematical and Fundamental Sciences\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.5000,\"publicationDate\":\"2024-05-21\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Mathematical and Fundamental Sciences\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.5614/j.math.fund.sci.2023.55.2.6\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"MULTIDISCIPLINARY SCIENCES\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Mathematical and Fundamental Sciences","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.5614/j.math.fund.sci.2023.55.2.6","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"MULTIDISCIPLINARY SCIENCES","Score":null,"Total":0}
Structural and Photoluminescence Properties of Ca2+-Substituted Self-Activated Photoluminescence Material of Na2TiSiO5
The effects of Ca2+ substitution on the structural and optical properties of Na2TiSiO5 were studied. It was expected that the Ca2+ ions would replace Na+ ions and change the coordination of Ti4+-O2- as a luminescence center. Na2(1‑x)CaxTiSiO5 (x = 0.00, 0.50, 1.00) samples were synthesized using the solid-state method, and their structural properties, the local Ti4+-O2- coordination, the absorption spectra, and the photoluminescence properties were studied. The electronic structure of Na2(1-x)CaxTiSiO5 with x = 0.00 and 1.00 was also calculated using the Full Potential Linear Augmented Plane Wave (FP-LAPW) method to explain some of the observed properties. The Ca2+ substitution resulted in a phase transformation from an orthorhombic to a monoclinic structure. The number of TiO6 octahedra increased with the increase of Ca2+ and correlated with the decrease of PL emission intensity of the Na2(1‑x)CaxTiSiO5 samples. The Ti-3d bands in the CaTiSiO5 were more dispersive than in the Na2TiSiO5 and were responsible for the PL emission intensity reduction.
期刊介绍:
Journal of Mathematical and Fundamental Sciences welcomes full research articles in the area of Mathematics and Natural Sciences from the following subject areas: Astronomy, Chemistry, Earth Sciences (Geodesy, Geology, Geophysics, Oceanography, Meteorology), Life Sciences (Agriculture, Biochemistry, Biology, Health Sciences, Medical Sciences, Pharmacy), Mathematics, Physics, and Statistics. New submissions of mathematics articles starting in January 2020 are required to focus on applied mathematics with real relevance to the field of natural sciences. Authors are invited to submit articles that have not been published previously and are not under consideration elsewhere.