Al1.5Fe3Co3Cr1 多主元素合金磁性能的显微结构依赖性

Metals Pub Date : 2024-05-21 DOI:10.3390/met14060608
Shaoheng Sun, Yaxia Qiao, Hao Zhang, Dejun Tu, Guojun Wang, Zhenhua Wang, Qing Wang
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引用次数: 0

摘要

本研究的重点是 Al1.5Fe3Co3Cr1 多主元素合金(MPEA)在不同状态下的微观结构和软磁特性。MPEA 采用电弧熔炼和吸铸工艺制备,然后经过各种热处理。利用 X 射线衍射(XRD)分析了晶体结构,并通过透射电子显微镜(TEM)和扫描电子显微镜(SEM)对微观结构进行了表征。结果表明,MPEA 主要由相干的体心立方(BCC)相和 B2 相组成,它们之间存在适度的晶格错配(ε = 0.14~0.21%)。均质合金中存在粗大的等轴晶粒和微尺度晶胞,具有良好的软磁特性,MS = 127 emu/g,HC = 143.3 A/m (1.8 Oe)。在 873 K 温度下老化后,合金的热稳定性达到最佳状态,微观结构和软磁特性没有发生显著变化。然而,当老化温度升高到 973 K 时,BCC 纳米沉淀物变得粗糙,导致软磁特性下降。
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Microstructure Dependence of Magnetic Properties for Al1.5Fe3Co3Cr1 Multi-Principal-Element Alloy
This study focuses on the microstructures and soft-magnetic properties of the Al1.5Fe3Co3Cr1 multi-principal-element alloy (MPEA) in different states. The MPEA was prepared using arc melting and suction-casting, followed by various heat treatments. The crystal structures were analyzed using X-ray diffraction (XRD), while the microstructures were characterized by means of transmission electron microscopy (TEM) and scanning electron microscopy (SEM). The results reveal that the MPEA consists mainly of coherent body-centered cubic (BCC) and B2 phases, with a moderate lattice misfit (ε = 0.14~0.21%) between them. The homogenized alloy shows the presence of coarse equiaxed grains and micro-scale cells, and it has good soft-magnetic properties with MS = 127 emu/g and HC = 143.3 A/m (1.8 Oe). The thermal stability of the alloy is found to be optimal after aging at 873 K, as there are no significant changes in microstructures and soft-magnetic properties. However, when the aging temperature increases to 973 K, the BCC nanoprecipitates are coarsened, leading to a decrease in the soft-magnetic properties.
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