用于光子应用的具有增强电光特性的二元向列液晶混合物

Ghada Hassanein, Omaima Alhaddad, Mostafa Ellabban
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摘要

目的:在这项工作中,我们混合了两种简单的向列液晶(NLC),并研究了不同混合比的 7CB/PCH5 二元向列液晶混合物。研究方法:采用差示扫描量热法对纯液晶 7CB 和 PCH5 以及它们的二元混合物进行了热分析。7CB/PCH5:30/70 wt%混合物的热稳定性最高,向列-各向同性(N-I)转变温度为 50oC。通过将潜水峰值电压从 0 V 提高到 10 V,使用振幅调制电信号(1 kHz - 100 Hz)研究了 7CB、PCH5 和 7CB/PCH5:30/70 wt% 混合物在室温下的电光特性。与纯 LC 相比,7CB/PCH5:30/70 wt% 混合物的响应时间最快,总响应时间为 2.36 ms,上升时间为 0.41 ms,下降时间为 1.95 ms。 它的对比度也最高。 此外,在 2V/mm 的场强下,它的最大测量透射率比 PCH5 和 7CB 分别高出约 17% 和 8%。研究结果研究结果表明,当与适当比例的 7CB 混合时,PCH5 的电光特性得到了改善,其成本更低、更稳定,在光子应用方面具有更大的潜力。对理论、实践和政策的独特贡献:这项实验研究表明,只需将两种成本相对较低的 NLCs 材料(一种具有较高的热稳定性和较低的电光性能,另一种具有较低的热稳定性和较好的电光性能)混合在一起,就能提高二元混合物的稳定性、响应性和透射率。如果采用适当的驱动方法,而不掺杂其他有机或无机材料,就能提高二元混合物的稳定性、响应性和透光性。
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Binary Nematic Liquid Crystals Mixture with Enhanced Electro-Optics Properties for Photonic Applications
Purpose: In this work, we mix two simple nematic liquid crystals (NLCs) and investigated the binaryNLCs mixtures of 7CB/PCH5 of different mixing ratios. Methodology: The pure liquid crystals 7CB and PCH5 and binary mixtures of them of high temperature stability were thermally analyzed by differential scanning calorimetry. The mixture 7CB/PCH5:30/70 wt% has the highest thermal stability with a nematic-isotropic (N-I) transition temperature at 50oC. The electrooptic properties of 7CB, PCH5, and the mixture 7CB/PCH5:30/70 wt% at room temperature were also investigated using an amplitude modulated electric signal (1 kHz - 100 Hz) by increasing diving peak voltage from 0 V to 10 V. The threshold volage is relatively reduced for the binary mixture in comparison to that value for PCH5. In comparison to the pure LCs,  the mixture 7CB/PCH5:30/70 wt% has the fastest response times of values 2.36 ms total time response, 0.41 ms rise time, and 1.95 ms fall time.  It has also the highest contrast ratio.  Moreover, it has a maximum measured transmission that is higher than those for PCH5 and 7CB by about 17 % and 8%, respectively, at a field strength of 2V/mm. Findings: The obtained results indicate that the electrooptic properties of PCH5 was improved when mixed with a proper ratio of 7CB, of  lower cost, more stablity , and higher potential for photonic applications. Unique Contriburibution to Theory, Practice and Policy: This expermental study shows that simply  by mixing two relatively low cost NLCs materials, one of high thermal stability  and low electro-optic properties with other one of low thermal stability and better electro-optic properties; this would improve the stability, response, and transmition of the binary mixture. If the a suitable driving method is applied, without doping with other orgnic or inorganic matrial.
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