基于近红外光谱指纹图谱的印度东北部和印度市场生姜粉的快速质量评估和可追溯性。

IF 3 3区 生物学 Q2 BIOCHEMICAL RESEARCH METHODS Phytochemical Analysis Pub Date : 2025-03-01 Epub Date: 2024-05-27 DOI:10.1002/pca.3397
Sirsha Naskar, Dilip Sing, Subhadip Banerjee, Anastasiia Shcherbakova, Amitabha Bandyopadhyay, Amit Kar, Pallab Kanti Haldar, Nanaocha Sharma, Pulok Kumar Mukherjee, Rajib Bandyopadhyay
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引用次数: 0

摘要

导言:生姜(Zingiber officinale Rosc.)由于植物化学物质的浓度和地理来源不同而存在很大差异。快速无创的质量和可追溯性评估技术可确保可持续的价值链:本研究的目的是根据从印度东北部和印度市场收集的干姜样品的光谱指纹,使用近红外光谱仪开发合适的机器学习模型来估算 6-姜酚的浓度并检查可追溯性:方法:对来自市场和印度东北部的样本进行高效液相色谱分析,以估算 6-姜酚的含量。近红外光谱仪获取光谱数据。质量预测采用偏最小二乘法回归(PLSR),而基于指纹的溯源识别则采用主成分分析和 t 分布随机邻域嵌入(t-SNE)。采用 RMSE 和 R2 值评估了不同选择波长和光谱指纹的模型性能:波长为 1,100-1,250 nm 和 1,325-1,550 nm 的标准正态变异预处理光谱数据显示出最佳校准模型,校准均方根误差和 R2 C(校准决定系数)值分别为 0.87 和 0.897。预测均方根误差的较低值(0.24)和 R2 P(预测决定系数)的较高值(0.973)表明了所开发模型的有效性:所开发的印度生姜近红外光谱模型可预测 6-姜酚含量,并提供基于地理位置的可追溯性识别,以确保可持续的价值链,从而提高效率、成本效益、消费者信心、可持续采购、可追溯性和数据驱动决策。
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Rapid quality assessment and traceability of ginger powder from Northeast India and Indian market based on near infrared spectroscopic fingerprinting.

Introduction: Ginger (Zingiber officinale Rosc.) varies widely due to varying concentrations of phytochemicals and geographical origin. Rapid non-invasive quality and traceability assessment techniques ensure a sustainable value chain.

Objective: The objective of this study is the development of suitable machine learning models to estimate the concentration of 6-gingerol and check traceability based on the spectral fingerprints of dried ginger samples collected from Northeast India and the Indian market using near-infrared spectrometry.

Methods: Samples from the market and Northeast India underwent High Performance Liquid Chromatographic analysis for 6-gingerol content estimation. Near infrared (NIR) Spectrometer acquired spectral data. Quality prediction utilized partial least square regression (PLSR), while fingerprint-based traceability identification employed principal component analysis and t-distributed stochastic neighbor embedding (t-SNE). Model performance was assessed using RMSE and R2 values across selective wavelengths and spectral fingerprints.

Results: The standard normal variate pretreated spectral data over the wavelength region of 1,100-1,250 nm and 1,325-1,550 nm showed the optimal calibration model with root mean square error of calibration and R2 C (coefficient of determination for calibration) values of 0.87 and 0.897 respectively. A lower value (0.24) of root mean square error of prediction and a higher value (0.973) of R2 P (coefficient of determination for prediction) indicated the effectiveness of the developed model. t-SNE performed better clustering of samples based on geographical location, which was independent of gingerol content.

Conclusion: The developed NIR spectroscopic model for Indian ginger samples predicts the 6-gingerol content and provides geographical traceability-based identification to ensure a sustainable value chain, which can promote efficiency, cost-effectiveness, consumer confidence, sustainable sourcing, traceability, and data-driven decision-making.

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来源期刊
Phytochemical Analysis
Phytochemical Analysis 生物-分析化学
CiteScore
6.00
自引率
6.10%
发文量
88
审稿时长
1.7 months
期刊介绍: Phytochemical Analysis is devoted to the publication of original articles concerning the development, improvement, validation and/or extension of application of analytical methodology in the plant sciences. The spectrum of coverage is broad, encompassing methods and techniques relevant to the detection (including bio-screening), extraction, separation, purification, identification and quantification of compounds in plant biochemistry, plant cellular and molecular biology, plant biotechnology, the food sciences, agriculture and horticulture. The Journal publishes papers describing significant novelty in the analysis of whole plants (including algae), plant cells, tissues and organs, plant-derived extracts and plant products (including those which have been partially or completely refined for use in the food, agrochemical, pharmaceutical and related industries). All forms of physical, chemical, biochemical, spectroscopic, radiometric, electrometric, chromatographic, metabolomic and chemometric investigations of plant products (monomeric species as well as polymeric molecules such as nucleic acids, proteins, lipids and carbohydrates) are included within the remit of the Journal. Papers dealing with novel methods relating to areas such as data handling/ data mining in plant sciences will also be welcomed.
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