二维π共轭硼氧共价有机框架的电子结构

IF 2.1 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Structural Chemistry Pub Date : 2024-05-28 DOI:10.1007/s11224-024-02344-y
Qi Qi, Li Junfeng, Sun Yueming
{"title":"二维π共轭硼氧共价有机框架的电子结构","authors":"Qi Qi,&nbsp;Li Junfeng,&nbsp;Sun Yueming","doi":"10.1007/s11224-024-02344-y","DOIUrl":null,"url":null,"abstract":"<div><p>Boroxine covalent organic frameworks (boroxine COFs) can be referred to as two-dimension (2D) polymer networks with cores of boroxine connected with rigid linker and extended in x or y dimensions, which might be good candidates for organic electronic and luminescence material. However, the engineering COFs with improved charge transfer and conduction properties based on pore size and linker structure still confront various challenges. Here, we investigate the geometrical structure and electronic properties with linkers from phenyl to biphenyl and the replacement of H with F atom in 2D scale with the CRYTSTAL17 software at the density functional theory (DFT) level with the global-hybrid PBE0 functional and POB-TZVP basis set, using a 5 × 5 k-point mesh. The increased pore diameter reduced their energy gap. Replacing the F atom with the H atom lowered their VBMs and conduction band minimums (CBMs). Computation results can assist the experimental scientist in producing highly conductive 2D boroxine COFs.</p></div>","PeriodicalId":780,"journal":{"name":"Structural Chemistry","volume":null,"pages":null},"PeriodicalIF":2.1000,"publicationDate":"2024-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Electronic structures of two-dimensional π-conjugated boroxine covalent organic frameworks\",\"authors\":\"Qi Qi,&nbsp;Li Junfeng,&nbsp;Sun Yueming\",\"doi\":\"10.1007/s11224-024-02344-y\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Boroxine covalent organic frameworks (boroxine COFs) can be referred to as two-dimension (2D) polymer networks with cores of boroxine connected with rigid linker and extended in x or y dimensions, which might be good candidates for organic electronic and luminescence material. However, the engineering COFs with improved charge transfer and conduction properties based on pore size and linker structure still confront various challenges. Here, we investigate the geometrical structure and electronic properties with linkers from phenyl to biphenyl and the replacement of H with F atom in 2D scale with the CRYTSTAL17 software at the density functional theory (DFT) level with the global-hybrid PBE0 functional and POB-TZVP basis set, using a 5 × 5 k-point mesh. The increased pore diameter reduced their energy gap. Replacing the F atom with the H atom lowered their VBMs and conduction band minimums (CBMs). Computation results can assist the experimental scientist in producing highly conductive 2D boroxine COFs.</p></div>\",\"PeriodicalId\":780,\"journal\":{\"name\":\"Structural Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.1000,\"publicationDate\":\"2024-05-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Structural Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11224-024-02344-y\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Structural Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s11224-024-02344-y","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

摘要

硼氧共价有机框架(Boroxine covalent organic frameworks,简称硼氧框架)可以被称为二维(2D)聚合物网络,其核心是由刚性连接体连接并在 x 或 y 维上延伸的硼氧,可能是有机电子和发光材料的良好候选材料。然而,如何根据孔隙大小和连接体结构设计出具有更好电荷转移和传导性能的 COF,仍然面临着各种挑战。在此,我们利用 CRYTSTAL17 软件,在密度泛函理论(DFT)水平上,使用全局混合 PBE0 函数和 POB-TZVP 基集,使用 5 × 5 k 点网格,研究了从苯基到联苯的连接体以及用 F 原子取代 H 原子的二维尺度几何结构和电子特性。孔径的增大减小了它们的能隙。用 H 原子取代 F 原子降低了它们的 VBM 和导带最小值(CBM)。计算结果有助于实验科学家制备高导电性的二维硼氧 COF。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

摘要图片

摘要图片

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
Electronic structures of two-dimensional π-conjugated boroxine covalent organic frameworks

Boroxine covalent organic frameworks (boroxine COFs) can be referred to as two-dimension (2D) polymer networks with cores of boroxine connected with rigid linker and extended in x or y dimensions, which might be good candidates for organic electronic and luminescence material. However, the engineering COFs with improved charge transfer and conduction properties based on pore size and linker structure still confront various challenges. Here, we investigate the geometrical structure and electronic properties with linkers from phenyl to biphenyl and the replacement of H with F atom in 2D scale with the CRYTSTAL17 software at the density functional theory (DFT) level with the global-hybrid PBE0 functional and POB-TZVP basis set, using a 5 × 5 k-point mesh. The increased pore diameter reduced their energy gap. Replacing the F atom with the H atom lowered their VBMs and conduction band minimums (CBMs). Computation results can assist the experimental scientist in producing highly conductive 2D boroxine COFs.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Structural Chemistry
Structural Chemistry 化学-化学综合
CiteScore
3.80
自引率
11.80%
发文量
227
审稿时长
3.7 months
期刊介绍: Structural Chemistry is an international forum for the publication of peer-reviewed original research papers that cover the condensed and gaseous states of matter and involve numerous techniques for the determination of structure and energetics, their results, and the conclusions derived from these studies. The journal overcomes the unnatural separation in the current literature among the areas of structure determination, energetics, and applications, as well as builds a bridge to other chemical disciplines. Ist comprehensive coverage encompasses broad discussion of results, observation of relationships among various properties, and the description and application of structure and energy information in all domains of chemistry. We welcome the broadest range of accounts of research in structural chemistry involving the discussion of methodologies and structures,experimental, theoretical, and computational, and their combinations. We encourage discussions of structural information collected for their chemicaland biological significance.
期刊最新文献
Stabilization of cyclo-N6 by insertion into [18]-annulene: a DFT study Theoretical study of novel antipyrine derivatives as promising corrosion inhibitors for mild steel in an acidic environment Density functional theory studies the interaction of neopentane with functionalized porous graphene An analogous Twisted Little Tale on the significance of unusual infrared frequencies Topological relations between crystal structures: a route to predicting inorganic materials
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1