不含粘结剂的含碳铁矿球团在还原过程中的热压强度演变机理

Hong-tao Wang, Yi-bin Wang, Shi-xin Zhu, Qing-min Meng, Tie-jun Chun, Hong-ming Long
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摘要

在 "碳峰值、碳中和 "的大背景下,发展非高炉炼铁技术对钢铁工业的可持续发展具有重要的现实意义。含碳铁矿球团因其优异的自还原性成为直接还原炼铁的创新负担,而球团的热强度是影响其广泛应用的关键冶金性能。本文利用铁精矿和无烟煤制备了不含粘结剂的含碳铁矿球团(CIPWB),研究了还原过程中还原剂加入量、球团粒度、还原温度和时间对 CIPWB 热压强度的影响。同时,还揭示了 CIPWB 热强度演变的机理。结果表明,在低温还原过程(300-500 °C)中,CIPWB 的热压强度随球团尺寸的增大而线性增加,但随无烟煤比例的增加而逐渐降低。当含有 8%无烟煤的 CIPWB 在 300 ℃ 下还原 60 分钟时,随着球团尺寸从 8.04 mm 增加到 12.78 mm,球团的热强度从 13.24 N 增加到 31.88 N。此外,在高温还原过程(600-1150 °C)中,随着温度的升高,CIPWB 的热压强度先升高后降低,而随着无烟煤比例的升高,其热压强度以及最大强度所对应的温度都会降低。添加 18% 的无烟煤后,球团的热压强度在 800 °C 时达到最大值,即 35.00 N,在 1050 °C 时达到最小值,即 8.60 N。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Mechanism of thermal compressive strength evolution of carbon-bearing iron ore pellet without binders during reduction process

Against the background of “carbon peak and carbon neutrality,” it is of great practical significance to develop non-blast furnace ironmaking technology for the sustainable development of steel industry. Carbon-bearing iron ore pellet is an innovative burden of direct reduction ironmaking due to its excellent self-reducing property, and the thermal strength of pellet is a crucial metallurgical property that affects its wide application. The carbon-bearing iron ore pellet without binders (CIPWB) was prepared using iron concentrate and anthracite, and the effects of reducing agent addition amount, size of pellet, reduction temperature and time on the thermal compressive strength of CIPWB during the reduction process were studied. Simultaneously, the mechanism of the thermal strength evolution of CIPWB was revealed. The results showed that during the low-temperature reduction process (300–500 °C), the thermal compressive strength of CIPWB linearly increases with increasing the size of pellet, while it gradually decreases with increasing the anthracite ratio. When the CIPWB with 8% anthracite is reduced at 300 °C for 60 min, the thermal strength of pellet is enhanced from 13.24 to 31.88 N as the size of pellet increases from 8.04 to 12.78 mm. Meanwhile, as the temperature is 500 °C, with increasing the anthracite ratio from 2% to 8%, the thermal compressive strength of pellet under reduction for 60 min remarkably decreases from 41.47 to 8.94 N. Furthermore, in the high-temperature reduction process (600–1150 °C), the thermal compressive strength of CIPWB firstly increases and then reduces with increasing the temperature, while it as well as the temperature corresponding to the maximum strength decreases with increasing the anthracite ratio. With adding 18% anthracite, the thermal compressive strength of pellet reaches the maximum value at 800 °C, namely 35.00 N, and obtains the minimum value at 1050 °C, namely 8.60 N. The thermal compressive strength of CIPWB significantly depends on the temperature, reducing agent dosage, and pellet size.

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来源期刊
自引率
16.00%
发文量
161
审稿时长
2.8 months
期刊介绍: Publishes critically reviewed original research of archival significance Covers hydrometallurgy, pyrometallurgy, electrometallurgy, transport phenomena, process control, physical chemistry, solidification, mechanical working, solid state reactions, materials processing, and more Includes welding & joining, surface treatment, mathematical modeling, corrosion, wear and abrasion Journal of Iron and Steel Research International publishes original papers and occasional invited reviews on aspects of research and technology in the process metallurgy and metallic materials. Coverage emphasizes the relationships among the processing, structure and properties of metals, including advanced steel materials, superalloy, intermetallics, metallic functional materials, powder metallurgy, structural titanium alloy, composite steel materials, high entropy alloy, amorphous alloys, metallic nanomaterials, etc..
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