Review on High Phosphorous in Iron Ore: Problem and Way Out

Phosphorous is an undesired element present in iron ore used in the steel making process. It leads to an increase in overall production cost as well as deteriorated steel quality. The desired phosphorus content in iron ores used in steel making is < 0.1%. Numerous beneficiation studies are mentioned in the literature; however, there is no commercial scale technology established to beneficiate high phosphorous iron. The major phosphorous bearing minerals are apatite (Ca₅(PO₄)(Cl/F/OH), wavellite (Al₃(PO₄)₂(OH)₃·5(H₂O)), senegalite (Al₂(PO₄)(OH)₃(H₂O), barrandite ((Fe,Al)PO₄·2H₂O), etc. Ultrafine grinding is required to liberate phosphorous minerals from iron ore minerals and subsequently subject it to flotation, acid leaching, and bioprocessing. The selective flotation of iron ore could successfully reduce the phosphorous content from 0.82% to < 0.20% with the combination of grinding, magnetic separation, and carbothermic reduction. Acid leaching processes are also able to remove ~80% (0.85%→0.16%) of phosphorus; however, these are relatively costly and complex processes. The mechanism of bio-extraction for phosphorous removal is reported as one of the most successful processes. This process is capable of removing more than 80% of the total phosphorous and significantly reducing the phosphorous content from 1.06% to 0.16%. The main disadvantage of this process is that it occurs at a much slower pace. In today’s scenario, ultrafine grinding followed by froth flotation seems to be the most feasible solution for the beneficiation of high phosphorous iron ore in which the concentrate obtained can be utilized for pellet making and ultimately used for steel making processes. Development of additives for leaching, roasting, and bioprocessing can be explored further to make these processes more effective and economically viable.