{"title":"脉冲激光沉积合成的无定形氮化碳薄膜上的水吸附作用","authors":"Kamal Kayed","doi":"10.1007/s10450-024-00500-8","DOIUrl":null,"url":null,"abstract":"<div><p>In this work, we investigate the structural parameters that affect water adsorption on amorphous carbon nitride thin films synthesized by pulsed laser deposition. The study includes the case of ablation of graphite targets within molecular nitrogen and within a stream of nitrogen plasma afterglow. The results obtained showed that, the effect of Csp<sup>2</sup>-Csp<sup>2</sup> bonds concentration on the adsorption of water molecules depends strongly on the ratio and distortion of the hexagonal rings. Furthermore, analysis of the spectral data showed that, the relationship between the hydrogen bonding strength of water molecules with the film surface and the concentration of Csp<sup>2</sup>-Csp<sup>2</sup> bonds takes a specific mathematical formula in the case of structures composed mainly of hexagonal rings.</p></div>","PeriodicalId":458,"journal":{"name":"Adsorption","volume":"30 6","pages":"1205 - 1212"},"PeriodicalIF":3.0000,"publicationDate":"2024-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Water adsorption on amorphous carbon nitride thin films synthesized by pulsed laser deposition\",\"authors\":\"Kamal Kayed\",\"doi\":\"10.1007/s10450-024-00500-8\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>In this work, we investigate the structural parameters that affect water adsorption on amorphous carbon nitride thin films synthesized by pulsed laser deposition. The study includes the case of ablation of graphite targets within molecular nitrogen and within a stream of nitrogen plasma afterglow. The results obtained showed that, the effect of Csp<sup>2</sup>-Csp<sup>2</sup> bonds concentration on the adsorption of water molecules depends strongly on the ratio and distortion of the hexagonal rings. Furthermore, analysis of the spectral data showed that, the relationship between the hydrogen bonding strength of water molecules with the film surface and the concentration of Csp<sup>2</sup>-Csp<sup>2</sup> bonds takes a specific mathematical formula in the case of structures composed mainly of hexagonal rings.</p></div>\",\"PeriodicalId\":458,\"journal\":{\"name\":\"Adsorption\",\"volume\":\"30 6\",\"pages\":\"1205 - 1212\"},\"PeriodicalIF\":3.0000,\"publicationDate\":\"2024-06-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Adsorption\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10450-024-00500-8\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Adsorption","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1007/s10450-024-00500-8","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Water adsorption on amorphous carbon nitride thin films synthesized by pulsed laser deposition
In this work, we investigate the structural parameters that affect water adsorption on amorphous carbon nitride thin films synthesized by pulsed laser deposition. The study includes the case of ablation of graphite targets within molecular nitrogen and within a stream of nitrogen plasma afterglow. The results obtained showed that, the effect of Csp2-Csp2 bonds concentration on the adsorption of water molecules depends strongly on the ratio and distortion of the hexagonal rings. Furthermore, analysis of the spectral data showed that, the relationship between the hydrogen bonding strength of water molecules with the film surface and the concentration of Csp2-Csp2 bonds takes a specific mathematical formula in the case of structures composed mainly of hexagonal rings.
期刊介绍：
The journal Adsorption provides authoritative information on adsorption and allied fields to scientists, engineers, and technologists throughout the world. The information takes the form of peer-reviewed articles, R&D notes, topical review papers, tutorial papers, book reviews, meeting announcements, and news.
Coverage includes fundamental and practical aspects of adsorption: mathematics, thermodynamics, chemistry, and physics, as well as processes, applications, models engineering, and equipment design.
Among the topics are Adsorbents: new materials, new synthesis techniques, characterization of structure and properties, and applications; Equilibria: novel theories or semi-empirical models, experimental data, and new measurement methods; Kinetics: new models, experimental data, and measurement methods. Processes: chemical, biochemical, environmental, and other applications, purification or bulk separation, fixed bed or moving bed systems, simulations, experiments, and design procedures.
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