Alexander Linke, Hans-Joachim Drexler and Torsten Beweries*,
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A Dinuclear Ir(III) Bis(thiophosphinite) Complex Formed by Unusual meta-C–H Activation at a Pincer Ligand
Oxidative addition of PC(H)P pincer ligands at late transition metals typically occurs via C–H activation in the 2-position of the ligand, yielding [(PCP)MHX] type pincer complexes (X = monoanionic ligand). We present formation of the dinuclear Ir(III) complex [(iPrPSCSPiPr)Ir(H)(MeCN)2]2[OTf]2 as a rare example of meta-C–H activation at a pincer ligand.
期刊介绍：
Organometallics is the flagship journal of organometallic chemistry and records progress in one of the most active fields of science, bridging organic and inorganic chemistry. The journal publishes Articles, Communications, Reviews, and Tutorials (instructional overviews) that depict research on the synthesis, structure, bonding, chemical reactivity, and reaction mechanisms for a variety of applications, including catalyst design and catalytic processes; main-group, transition-metal, and lanthanide and actinide metal chemistry; synthetic aspects of polymer science and materials science; and bioorganometallic chemistry.
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