ZG13Cr9Mo1VNbN 不锈钢与铬铁矿砂之间的界面行为

Shi-sen Li, Xi-min Zang, Ji-lin Chen, Jie Yang, Yu-an Jing, Zhi-ying Wang, Ling-zhong Kong
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摘要

为了阐明砂型铸造过程中烧砂和金属渗透的形成机制,在不同温度(1813、1833、1853 和 1873 K)和保温时间(20、40、60 和 90 分钟)下进行了一些实验室实验,以模拟 ZG13Cr9Mo1VNbN 不锈钢和铬铁矿砂之间的相互作用。结果表明,缺陷主要由液相、铬铁矿和金属的混合物组成。液相的主要成分是 SiO2、MnO、MgO、Cr2O3、FeO 和 Al2O3,并发现 Cr2O3 是通过界面氧化还原反应形成的。液相的存在在影响烧结砂和金属渗透方面起着关键作用。界面反应具有优先性,而烧结砂的影响仍占主导地位。随着砂中液相数量的增加,金属渗透的发生率也会相应增加。即使钢中含有极少量的硅元素,也会影响液相的形成。此外,铬铁矿砂的分解或溶解也是产生烧结砂和金属渗透的一个重要因素。因此,彻底调查这种现象的条件和诱因对于有效管理和缓解这种现象至关重要。
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Interfacial behaviors between ZG13Cr9Mo1VNbN stainless steel and chromite sand

To elucidate the formation mechanisms of burn-on sand and metal penetration during sand casting, some laboratory experiments were carried out at different temperatures (1813, 1833, 1853, and 1873 K) and holding time (20, 40, 60, and 90 min) to simulate the interaction between ZG13Cr9Mo1VNbN stainless steel and chromite sand. The results demonstrate that the defects primarily consist of a mixture of the liquid phase, chromite, and metal. The main components of the liquid phase are SiO2, MnO, MgO, Cr2O3, FeO, and Al2O3, and the formation of Cr2O3 through interfacial redox reactions has been discovered. The presence of a liquid phase plays a pivotal role in influencing burn-on sand and metal penetration. Interface reactions are prioritized, with burn-on sand maintaining a predominant influence. As the liquid phase quantity within the sand escalates, there is a corresponding incremental rise in the incidence of metal penetration. Even a minimal presence of the silicon element in steel can impact the liquid phase’s formation. Moreover, the decomposition or dissolution of chromite sand is a significant factor in the development of burn-on sand and metal penetration. Thus, a thorough investigation into the conditions and contributing factors of this phenomenon is essential for its effective management and mitigation.

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来源期刊
自引率
16.00%
发文量
161
审稿时长
2.8 months
期刊介绍: Publishes critically reviewed original research of archival significance Covers hydrometallurgy, pyrometallurgy, electrometallurgy, transport phenomena, process control, physical chemistry, solidification, mechanical working, solid state reactions, materials processing, and more Includes welding & joining, surface treatment, mathematical modeling, corrosion, wear and abrasion Journal of Iron and Steel Research International publishes original papers and occasional invited reviews on aspects of research and technology in the process metallurgy and metallic materials. Coverage emphasizes the relationships among the processing, structure and properties of metals, including advanced steel materials, superalloy, intermetallics, metallic functional materials, powder metallurgy, structural titanium alloy, composite steel materials, high entropy alloy, amorphous alloys, metallic nanomaterials, etc..
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