麦科普系列岩石和泥火山粘土对汞(II)的吸附作用

IF 0.3 Q4 GEOLOGY Moscow University Geology Bulletin Pub Date : 2024-06-05 DOI:10.3103/s014587522470011x
D. S. Salavatova, D. A. Bychkov, R. V. Fiaizullina
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引用次数: 0

摘要

摘要 研究了麦科普系列粘土和泥火山粘土表面的酸碱特性及其对汞(II)离子的吸附特性。结果表明,前者的 pHPZC 平均为 7.1,后者为 9.0。泥火山粘土的 pHPZC 值与刻赤塔曼地区泥火山水域的 pH 值一致。当吸附剂和溶液的质量比为 1 : 900 时,在积极搅拌下,4 天后就会达到吸附平衡。天然吸附剂对 NaCl-NaHCO3 溶液中汞的吸附实验数据用 Redlich-Peterson 和 Toth 方程进行了最佳描述。汞在 Maikop 系列粘土上的吸附过程比在泥火山粘土上更为强烈。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Mercury(II) Adsorption on the Maikop Series Rocks and Mud Volcano Clays

Abstract

The acid–base properties of the surface of Maikop series clays and mud volcano clays, as well as their adsorption properties with respect to mercury(II) ions, were studied. It is shown that pHPZC for the former is 7.1 on average; for the latter, 9.0. The pHPZC value for mud volcano clays is consistent with the pH values in the waters of mud volcanoes of the Kerch–Taman region. When the mass ratio of the sorbent and solution is 1 : 900, adsorption equilibrium occurs after 4 days with active stirring. Experimental data on mercury adsorption from NaCl–NaHCO3 solution on natural sorbents are best described by the Redlich–Peterson and Toth equations. The process of mercury adsorption on clays of the Maikop series is more intense than that on mud volcano clays.

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来源期刊
CiteScore
0.60
自引率
25.00%
发文量
43
期刊介绍: Moscow University Geology Bulletin  is the journal that mainly publishes scientific articles, short reports of graduate students, and reviews. Publications made by the members of the Faculty of Geology of the Moscow State University and their collaborators are published. Publications encompass all branches of geology.
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