A Novel Method to Enhance the Content and size of Y-211 Particles in YBCO bulk Superconductors Grown by RE+011 TSIG Process

In this research, a novel method to improve the particle size and content of Y₂BaCuO₅ (Y-211) in YBa₂Cu₃O_7 − x (YBCO) bulks was demonstrated. The single-domain YBCO bulks (20 mm in diameter) have been fabricated employing the RE+011 TSIG technique with different heating rates during the liquid phase infiltration (LPI) stage. The various heating rates on Y-211 size and its content in the final YBCO samples has been investigated in detail. The findings suggest that the average size of the Y-211 particles in the Y-123 matrix initially decreases followed by an increase, while its volume fraction gradually decreases with increasing heating rate. Furthermore, it is observed that the levitation force and the trapped fields exhibit an initial increase followed by a subsequent decrease as the heating rate increases. Among all the samples, sample S3 (heating rate of 30 °C/h) has the best magnetic levitation force and trapped field performances at 77 K, i.e., the largest values are of 45.3 N and 0.41 T, respectively. The results suggest that, while employing the RE+011 TSIG technique for YBCO bulk fabrication, the average size and volume fraction of Y-211 particles in the final sample can be further enhanced by controlling the heating rates during the LPI stage, obviating any need for chemical refining agents.