{"title":"深共晶溶剂作为材料制备的绿色溶剂","authors":"Dongkun Yu , Depeng Jiang , Zhimin Xue , Tiancheng Mu","doi":"10.1039/d4gc00136b","DOIUrl":null,"url":null,"abstract":"<div><p>The concept of sustainability has progressively evolved into a consensus for achieving long-term development, and the significance of solvents in regard to green chemistry and sustainable processes cannot be underestimated. Hydrogen-bonding interactions and heterogeneity at the nanoscale determine the outstanding solvating properties of deep eutectic solvents (DESs). A relatively wide electrochemical window is the prerequisite for the preparation of more materials (especially active metals) by electrodeposition in these eutectic systems. The role of DESs in the fabrication process may be chemical or physical, although the line between the two is blurred. At times, DESs function as a reducing agent, while in other cases they solely provide a liquid environment to facilitate the reaction. This review provides a set of methodologies to guide the preparation of materials with specific morphology and functions.</p></div>","PeriodicalId":78,"journal":{"name":"Green Chemistry","volume":"26 13","pages":"Pages 7478-7507"},"PeriodicalIF":9.3000,"publicationDate":"2024-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Deep eutectic solvents as green solvents for materials preparation\",\"authors\":\"Dongkun Yu , Depeng Jiang , Zhimin Xue , Tiancheng Mu\",\"doi\":\"10.1039/d4gc00136b\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The concept of sustainability has progressively evolved into a consensus for achieving long-term development, and the significance of solvents in regard to green chemistry and sustainable processes cannot be underestimated. Hydrogen-bonding interactions and heterogeneity at the nanoscale determine the outstanding solvating properties of deep eutectic solvents (DESs). A relatively wide electrochemical window is the prerequisite for the preparation of more materials (especially active metals) by electrodeposition in these eutectic systems. The role of DESs in the fabrication process may be chemical or physical, although the line between the two is blurred. At times, DESs function as a reducing agent, while in other cases they solely provide a liquid environment to facilitate the reaction. This review provides a set of methodologies to guide the preparation of materials with specific morphology and functions.</p></div>\",\"PeriodicalId\":78,\"journal\":{\"name\":\"Green Chemistry\",\"volume\":\"26 13\",\"pages\":\"Pages 7478-7507\"},\"PeriodicalIF\":9.3000,\"publicationDate\":\"2024-07-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Green Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S1463926224005922\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Green Chemistry","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S1463926224005922","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Deep eutectic solvents as green solvents for materials preparation
The concept of sustainability has progressively evolved into a consensus for achieving long-term development, and the significance of solvents in regard to green chemistry and sustainable processes cannot be underestimated. Hydrogen-bonding interactions and heterogeneity at the nanoscale determine the outstanding solvating properties of deep eutectic solvents (DESs). A relatively wide electrochemical window is the prerequisite for the preparation of more materials (especially active metals) by electrodeposition in these eutectic systems. The role of DESs in the fabrication process may be chemical or physical, although the line between the two is blurred. At times, DESs function as a reducing agent, while in other cases they solely provide a liquid environment to facilitate the reaction. This review provides a set of methodologies to guide the preparation of materials with specific morphology and functions.
期刊介绍:
Green Chemistry is a journal that provides a unique forum for the publication of innovative research on the development of alternative green and sustainable technologies. The scope of Green Chemistry is based on the definition proposed by Anastas and Warner (Green Chemistry: Theory and Practice, P T Anastas and J C Warner, Oxford University Press, Oxford, 1998), which defines green chemistry as the utilisation of a set of principles that reduces or eliminates the use or generation of hazardous substances in the design, manufacture and application of chemical products. Green Chemistry aims to reduce the environmental impact of the chemical enterprise by developing a technology base that is inherently non-toxic to living things and the environment. The journal welcomes submissions on all aspects of research relating to this endeavor and publishes original and significant cutting-edge research that is likely to be of wide general appeal. For a work to be published, it must present a significant advance in green chemistry, including a comparison with existing methods and a demonstration of advantages over those methods.